A palladium polyaniline complex: a simple and efficient catalyst for batch and flow Suzuki–Miyaura cross-couplings

Abstract

A novel palladium polyaniline complex (Pd@PANI) was synthesized via one-pot method using low concentration hydrogen peroxideas (3 wt.%) as mild oxidants. The Pd@PANI was employed to catalyze Suzuki-Miyaura cross-couplings with...

Rapid mild macrocyclization of depsipeptides under continuous flow: total syntheses of five cyclodepsipeptides

“…Because of our research interests in the area of drug synthesis and flow applications, [29][30][31][32][33][34][35] we devoted our efforts to the synthesis of cyclodepsipeptides. Herein, we described a rapid, mild, and efficient macrocyclization process of depsipeptides under continuous flow to accomplish the total synthesis of five destruxin analogues (Fig.…”

Nickel-Catalyzed Suzuki Coupling of Phenols Enabled by SuFEx of Tosyl Fluoride

“…The following supporting information can be downloaded at: , Characterization data and copies of 1 H & 13 C NMR spectra of products (References [ 21 , 42 , 43 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 ] are cited in the Supplementary Materials).…”