A phenomenological and quantitative view on the degradation of positive electrodes from spent lithium-ion batteries in humid atmosphere

Abstract

The present study deals with the phenomenological observation of the corrosion of the positive electrode foil of lithium-ion batteries containing LiNi0.6Co0.2Mn0.2O2 (NMC) as cathode material. Due to the presence of moisture, localized water accumulation is formed on the NMC surface. The water absorbed by the electrolyte reacts with the NMC under Li+/H+ exchange and the resulting pH increase leads to dissolution of the carrier foil and characteristic salt-like blooms on the NMC surface. With the increase in the relative area occupied by the holes in the aluminum foil per time, a sufficiently suitable parameter was found with which to quantitatively determine the extent of corrosion. The degree of degradation depends on time and ambient humidity. It was shown that functional recycling with the water jet method is no longer applicable for degraded foils, since the mechanical stability of the foils decreases as corrosion progresses. Lithium, aluminum, sulfur and oxygen were detected in the blooms using SEM–EDX and Laser-Induced-Breakdown-Spectroscopy (LIBS). The underlying NMC layer was found to contain mainly aluminum and significantly lower lithium content than the non-degraded material. SEM and Raman microscopy analyses also showed that the active material is also locally degraded and therefore no longer suitable for functional recycling.

Engineering Polymer-Based Porous Membrane for Sustainable Lithium-Ion Battery Separators

“…LIBs are mainly composed of positive (cathode) and negative (anode) electrodes [ 13 , 14 ], electrolytes, and separators [ 15 , 16 , 17 , 18 , 19 ], wherein the separator, mainly consisting of a porous membrane material, assumes an indispensable and critical role within LIBs ( Figure 1 ). The porous membrane absorbs electrolytes and is assembled between the battery cathode and anode electrodes, which is a crucial section in LIB separators [ 9 , 20 ]. Throughout the charging and discharging cycles of LIBs, lithium ions (Li + ) migrate between the cathode and anode electrodes through a separator and, thus, conduct electricity [ 21 ].…”