A plant-based reactive ammonium phytate for use as a flame-retardant for cotton fabric

Feng, Ying; Zhou, Yang; Li, Daikun; He, Shuai; Zhang, Fengxiu; Zhang, Guang‐Xian

doi:10.1016/j.carbpol.2017.06.129

Cited by 148 publications

(84 citation statements)

References 42 publications

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“…However, cotton fabrics are extremely flammable, threatening human life and property . The flame retardant cotton fabric can delay the spread of flame; furthermore, it can improve the flame‐retardant, self‐extinguishing and smoke‐eliminating properties of cotton fabrics …”

Section: Introductionmentioning

confidence: 99%

A Phosphorous‐Aluminium‐Nitride Synergistic Flame Retardant to Enhance Durability and Flame Retardancy of Cotton

et al. 2019

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In this paper, a Phosphorous ‐ Aluminium ‐ Nitride synergistic flame retardant (PAN) was synthesized by phosphoric acid, glycerol, aluminium sulfate and urea, though a one‐pot process. The PAN was durably grafted onto the surface of cotton fabric by the simple process of soak‐dry‐cure. At the same time, the synergistic effect of the aluminium element and Phosphorous ‐ Nitrogen flame retardants (PN) was investigated. The flame‐retardant effect is the best when the conttent of alumium is 2.5 mol% (percentage of phosphoricacid) in PAN. The analyses of FTIR and XPS results suggested that PAN was grafted onto the cotton by forming a strong P−O‐C covalent bond on the surface of fiber. The SEM and Whiteness test proved that the flame‐retardant finishing cotton fabric do possess good morphology and whiteness. The thermal stability and flame retardancy of the PAN treated cotton fabric were assessed by TG and vertical flammability test. Then, found the aluminium sulfate in PAN had synergistic effect, and the PAN had significant flame retardancy in application.

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Section: Introductionmentioning

confidence: 99%

A Phosphorous‐Aluminium‐Nitride Synergistic Flame Retardant to Enhance Durability and Flame Retardancy of Cotton

et al. 2019

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“…Chitosan has recently been examined more broadly as an FR additive, working in concert with a broad range of inorganic additives [71] and phosphorous sources [72]. Phytic acid has similarly been shown by multiple workers to be a useful FR agent, working synergistically with tannic acid [73], or as a phytate salt with ammonia [74], metal ions [75], piperidine [76] or 1,6-hexane diamine [77]. Phytic acid is an intriguing additive in that it brings six phosphate groups per molecule, bound to a readily carbonizable glucose ring; many of the reported salts introduce nitrogen in their cations.…”

Section: Polymer Loimentioning

confidence: 99%

Biomolecules as Flame Retardant Additives for Polymers: A Review

Watson

Schiraldi

2020

Polymers

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Biological molecules can be obtained from natural sources or from commercial waste streams and can serve as effective feedstocks for a wide range of polymer products. From foams to epoxies and composites to bulk plastics, biomolecules show processability, thermal stability, and mechanical adaptations to fulfill current material requirements. This paper summarizes the known bio-sourced (or bio-derived), environmentally safe, thermo-oxidative, and flame retardant (BEST-FR) additives from animal tissues, plant fibers, food waste, and other natural resources. The flammability, flame retardance, and—where available—effects on polymer matrix’s mechanical properties of these materials will be presented. Their method of incorporation into the matrix, and the matrices for which the BEST-FR should be applicable will also be made known if reported. Lastly, a review on terminology and testing methodology is provided with comments on future developments in the field.

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“…图 14 (a) 氮改性硅烷杂化物的合成图; (b) LBL制备SiN/PA涂层原理图 [57] (网络版彩图) Leistner等 [59] 将Mel与CS制备成混合溶液, 通过 [58] (网络版彩图)…”

Section: 疏水性unclassified

Research progress of bio-based polymer flame retardant coating

Wu¹,

Chen²

2019

Sci. Sin.-Chim

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A plant-based reactive ammonium phytate for use as a flame-retardant for cotton fabric

Cited by 148 publications

References 42 publications

A Phosphorous‐Aluminium‐Nitride Synergistic Flame Retardant to Enhance Durability and Flame Retardancy of Cotton

A Phosphorous‐Aluminium‐Nitride Synergistic Flame Retardant to Enhance Durability and Flame Retardancy of Cotton

Biomolecules as Flame Retardant Additives for Polymers: A Review

Research progress of bio-based polymer flame retardant coating

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