A polyimide based all-organic sodium ion battery

Banda, Harish; Damien, D.; Nagarajan, Kalaivanan; Hariharan, Mahesh; Shaijumon, Manikoth M.

doi:10.1039/c5ta02043c

Cited by 160 publications

(135 citation statements)

References 41 publications

Supporting

Mentioning

126

Contrasting

Order By: Relevance

“…Imide groups, which are a type of carbonyl groups with anhydrides, were also recently investigated as Na organic cathodes. [261][262][263] A 3, 4, 9, 10-perylene-bis(dicarboximide) (PTCDI), which belongs to the perylene diimide group, was reported. [ 262 ] The electrode is insoluble in organic electrolytes and has multiple Na ion binding sites.…”

Section: Organic Cathodesmentioning

confidence: 99%

Recent Progress in Electrode Materials for Sodium‐Ion Batteries

Kim

Zhang

et al. 2016

Advanced Energy Materials

884

595

View full text Add to dashboard Cite

Grid‐scale energy storage systems (ESSs) that can connect to sustainable energy resources have received great attention in an effort to satisfy ever‐growing energy demands. Although recent advances in Li‐ion battery (LIB) technology have increased the energy density to a level applicable to grid‐scale ESSs, the high cost of Li and transition metals have led to a search for lower‐cost battery system alternatives. Based on the abundance and accessibility of Na and its similar electrochemistry to the well‐established LIB technology, Na‐ion batteries (NIBs) have attracted significant attention as an ideal candidate for grid‐scale ESSs. Since research on NIB chemistry resurged in 2010, various positive and negative electrode materials have been synthesized and evaluated for NIBs. Nonetheless, studies on NIB chemistry are still in their infancy compared with LIB technology, and further improvements are required in terms of energy, power density, and electrochemical stability for commercialization. Most recent progress on electrode materials for NIBs, including the discovery of new electrode materials and their Na storage mechanisms, is briefly reviewed. In addition, efforts to enhance the electrochemical properties of NIB electrode materials as well as the challenges and perspectives involving these materials are discussed.

show abstract

Section: Organic Cathodesmentioning

confidence: 99%

Recent Progress in Electrode Materials for Sodium‐Ion Batteries

Kim

Zhang

et al. 2016

Advanced Energy Materials

884

595

View full text Add to dashboard Cite

show abstract

“…42-45) [17,65] have been prepared for inhibiting the dissolution. 42-45) [17,65] have been prepared for inhibiting the dissolution.…”

Section: Imide and Polyimide Compoundsmentioning

confidence: 99%

Advanced Organic Electrode Materials for Rechargeable Sodium‐Ion Batteries

Zhao

Lü

Chen

2016

Advanced Energy Materials

481

322

View full text Add to dashboard Cite

Benefiting from the high abundance and low cost of sodium resource, rechargeable sodium‐ion batteries (SIBs) are regarded as promising candidates for large‐scale electrochemical energy storage and conversion. Due to the heavier mass and larger radius of Na+ than that of Li+, SIBs with inorganic electrode materials are currently plagued with low capacity and insufficient cycling life. In comparison, organic electrode materials display the advantages of structure designability, high capacity and low limitation of cationic radius. However, organic electrode materials also encounter issues such as high‐solubility in electrolyte and low conductivity. Here, recently reported organic electrode materials, which mainly include the reactions based on either carbon‐oxygen double bond or carbon‐nitrogen double bond, and doping reactions, are systematically reviewed. Furthermore, the design strategies of organic electrodes are comprehensively summarized. The working voltage is regulated through controlling the lowest unoccupied molecular orbital energies. The theoretical capacity can be enhanced by increasing the active groups. The dissolution is inhibited with elevating the intermolecular forces with proper molecular weight. The conductivity can be improved with extending conjugated structures. Future research into organic electrodes should focus on the development of full SIBs with aqueous/aprotic electrolytes and long cycling stability.

show abstract

“…This SIFC exhibits an operating voltage of about 1.4 V, with a cycling stability of 91.8% after 100 cycles. Other organics, such as Na 2 C 6 O 6 , polyimide, and all‐organic polymeric‐based SIFCs have also been investigated.…”

Section: Non‐aqueous Cathode‐based Sifcsmentioning

confidence: 99%

Emerging Prototype Sodium‐Ion Full Cells with Nanostructured Electrode Materials

Ren

Zhu

et al. 2017

Small

111

View full text Add to dashboard Cite

Due to steadily increasing energy consumption, the demand of renewable energy sources is more urgent than ever. Sodium-ion batteries (SIBs) have emerged as a cost-effective alternative because of the earth abundance of Na resources and their competitive electrochemical behaviors. Before practical application, it is essential to establish a bridge between the sodium half-cell and the commercial battery from a full cell perspective. An overview of the major challenges, most recent advances, and outlooks of non-aqueous and aqueous sodium-ion full cells (SIFCs) is presented. Considering the intimate relationship between SIFCs and electrode materials, including structure, composition and mutual matching principle, both the advance of various prototype SIFCs and the electrochemistry development of nanostructured electrode materials are reviewed. It is noted that a series of SIFCs combined with layered oxides and hard carbon are capable of providing a high specific gravimetric energy above 200 Wh kg , and an NaCrO //hard carbon full cell is able to deliver a high rate capability over 100 C. To achieve industrialization of SIBs, more systematic work should focus on electrode construction, component compatibility, and battery technologies.

show abstract

A polyimide based all-organic sodium ion battery

Cited by 160 publications

References 41 publications

Recent Progress in Electrode Materials for Sodium‐Ion Batteries

Recent Progress in Electrode Materials for Sodium‐Ion Batteries

Advanced Organic Electrode Materials for Rechargeable Sodium‐Ion Batteries

Emerging Prototype Sodium‐Ion Full Cells with Nanostructured Electrode Materials

Contact Info

Product

Resources

About