Access control data will continue to be exposed to the threat of privacy leakage even if blockchain technology currently offers a new solution for the security and privacy of the internet of things (IoT). However, its usability and privacy are not completely leveraged. This paper first discusses the IoT and blockchain technology and then examines each technology's structural models in order to address the issue of information security and privacy protection for the global organization IoT based on blockchain. Second, the information security and privacy guarantee system based on blockchain is built with ZKP and TEE at its heart after problems with zero-knowledge proof (ZKP) and trusted execution environment (TEE) in information security guarantee based on blockchain are investigated. By comparing the simulation trials, the proposed system's viability is finally confirmed. The results demonstrate that the suggested algorithm's evidence generation time is 352 ms when it reaches the experiment's highest node 28, which is clearly faster than previous techniques.