“…There are a number of modifications on the Saltzman method. One reported by Lyshkow (16) improves the rate of color development, sensitivity and longer shelf-life of the reagent by adding a promoter (11-salt), and optimizing the concentrations of diazotizing and coupling reagents. The R-salfc used was 2napthol-3,6-disulfonate.…”
Section: Determination By Photometry Of Azo Dyesmentioning
“…There are a number of modifications on the Saltzman method. One reported by Lyshkow (16) improves the rate of color development, sensitivity and longer shelf-life of the reagent by adding a promoter (11-salt), and optimizing the concentrations of diazotizing and coupling reagents. The R-salfc used was 2napthol-3,6-disulfonate.…”
Section: Determination By Photometry Of Azo Dyesmentioning
“…Figure 1a shows the UV-vis reflectance spectra of the GS-soaked pads exposed to different concentrations of NO2 for 5 min. The spectra are dominated by an asymmetric absorption band centered around 540 nm [3], which is the responsible of the characteristic deep-purple coloration developed by the GS reagent in presence of NO2. It was determined that the reflectance at 540 nm presented, approximately, an exponential dependence on the NO2 concentration.…”
Abstract:We present a simple an inexpensive method to implement a Griess-Saltzman-type reaction that combines the advantages of the liquid phase method (high specificity, fast response time) with the benefits of a solid implementation (easy to handle). We demonstrate that the measurements can be carried out using conventional RGB sensors; circumventing all the limitations around the measurement of the samples with spectrometers. We also present a method to optimize the measurement protocol and target a specific range of NO2 concentrations. We demonstrate that it is possible to measure the concentration of NO2 from 50 ppb to 300 ppm with high specificity and without modifying the sensing elements.
“…(5) This is a non-reversible process that consumes the available indicator molecules in the white state. Considering a 1 st order reaction in [INDW] and an n-th order reaction in [NO2 air] (NO2 involves a multi-step reaction such as hydrolyzation 14 and diazotization 15 ) the process can be modeled by the following set of equations:…”
We present a simple and inexpensive method to implement a Griess-Saltzman-type reaction that combines the advantages of the liquid phase method (high specificity and fast response time) with the benefits of a solid implementation (easy to handle). We demonstrate that the measurements can be carried out using conventional RGB sensors; circumventing all the limitations around the measurement of the samples with spectrometers. We also present a method to optimize the measurement protocol and target a specific range of NO concentrations. We demonstrate that it is possible to measure the concentration of NO from 50 ppb to 300 ppm with high specificity and without modifying the Griess-Saltzman reagent.
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