A Redox‐Active Phenothiazine‐based Pd2L4‐Type Coordination Cage and Its Isolable Crystalline Polyradical Cations
Bin Huang,
Manfei Zhou,
Qiong‐Yan Hong
et al.
Abstract:Polyradical cages are of great interest because they show very fascinating physical and chemical properties, but many challenges remain, especially for their synthesis and characterization. Herein, we present the synthesis of a polyradical cation cage 14•+ through post‐synthetic oxidation of a redox‐active phenothiazine‐based Pd2L4‐type coordination cage 1. It's worth noting that 1 exhibits excellent reversible electrochemical and chemical redox activity due to the introduction of a bulky 3,5‐di‐tert‐butyl‐4‐m… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.