1972
DOI: 10.1007/bf02270653
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A reexamination of liquid-solid adsorption in gas-liquid chromatography

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1973
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Cited by 12 publications
(2 citation statements)
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“…to eq 3 provides a direct experimental approach to the Vn*/Vl = Kl + (AglKgl + AlsKgls)( 1/Vl) (3) gas-liquid partition coefficient that requires only easily determined column parameters. [25][26][27][28][29]35,38,39 A plot of Un*/Ul vs 1/ Vh will be either a curve or straight line giving Kh as the intercept at 1/VL = 0. The shape of the plot is dependent on the relative importance of adsorption at the gas-liquid and gas-solid interfaces.…”
Section: Retention Mechanisms In Gas-liquid Chromatographymentioning
confidence: 99%
“…to eq 3 provides a direct experimental approach to the Vn*/Vl = Kl + (AglKgl + AlsKgls)( 1/Vl) (3) gas-liquid partition coefficient that requires only easily determined column parameters. [25][26][27][28][29]35,38,39 A plot of Un*/Ul vs 1/ Vh will be either a curve or straight line giving Kh as the intercept at 1/VL = 0. The shape of the plot is dependent on the relative importance of adsorption at the gas-liquid and gas-solid interfaces.…”
Section: Retention Mechanisms In Gas-liquid Chromatographymentioning
confidence: 99%
“…Adsorption in GLC was also treated in terms of its effect on retention (292). However, Eon, Chatterjee, and Karger (243) pointed out that liquid-solid adsorption is not an important contributor to GLC.…”
mentioning
confidence: 99%