“…Generally speaking, when a layered RP perovskite is obtained the growth of layers among the direction oriented parallel to the substrate, namely, along the (00l) family of planes, is strongly favored [ 42 ] and the first member of the RP family ( n = 1) adopts a structure with only one layer of corner‐sharing octahedra [ 43–45 ] . However, at growing number of layers, (0 k 0) orientation appears, [ 12 ] as it is clearly detected upon the present films. Indeed, for both studied samples with bulky cation posttreatment, low‐angle diffraction peaks appear at 2 θ = 7.15° and 15.33°, corresponding, respectively, to the (040) and (060) 2D planes.…”