A Silver(I) Iodide Complex of a Tellurophosphorane

Nordheider, Andreas; Slawin, Alexandra M. Z.; Woollins, J. Derek; Chivers, Tristram

doi:10.1002/zaac.201400452

Cited by 7 publications

(5 citation statements)

References 12 publications

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“…Besides their utility as excellent ligands towards both main group [44][45][46][47][48][49] and transition elements, 23,50,51 cyclodiphosphazane derivatives have been employed in homogeneous catalysis, [52][53][54][55][56][57] antitumor studies, [58][59][60] in metal organic framework to form even sodalite type structures 61 and also in the isolation of stable biradicaloids with a rich chemistry. [62][63][64] The recently made cyclodiphosphazane based carbene 65,66 by Wright and co-workers highlights the versatility of cyclodiphosphazane scaffolds in the design of new generation ligand systems.…”

Section: Background To Cyclodiphosphazanes and Their Synthetic Method...mentioning

confidence: 99%

Cyclodiphosphazanes: options are endless

Balakrishna

2016

Dalton Trans.

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Cyclodiphosphazanes, also known as diazadiphosphetidines, are saturated inorganic ring systems containing alternating trivalent phosphorus and nitrogen atoms. With a rigid planar structure and moderately stable P-N bonds, cyclodiphosphazanes have shown versatility not only in coordination chemistry as both neutral and anionic ligands but also as useful scaffolds in supramolecular chemistry, resulting in a plethora of molecules with interesting structural features. Recent reports on their utility in generating several 3D-coordination polymers including those with sodalite structures, cyclodiphosphazane based N-heterocyclic carbenes and stable biradicaloids highlight the versatility of these novel phosphorus-nitrogen cyclic compounds. This review describes mainly the coordination chemistry of cyclodiphosphazanes as neutral ligands and their applications besides recent advances in cyclodiphosph(iii)azane chemistry. The key points on the empirical model proposed to highlight the coordinating ability of cyclodiphosphazanes to build soft-soft MOFs and an analysis of pertinent structural features are also presented.

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Section: Background To Cyclodiphosphazanes and Their Synthetic Method...mentioning

confidence: 99%

Cyclodiphosphazanes: options are endless

Balakrishna

2016

Dalton Trans.

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“…4 pm) than the bond distance of the free ligand (2.363(1) Å), 17 which could be attributed to coordination to the silver atom, as previously observed for other silver complexes. 16…”

Section: Resultsmentioning

confidence: 99%

Unravelling the role of triisopropylphosphane telluride in Ag(i) complexes

Pérez-Sánchez,

Ceamanos,

Herrera

et al. 2023

Inorg. Chem. Front.

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“…103 The 1 J( 31 P, 125 Te) value is reduced by > 300 Hz for this ligand in a bridging role, although the P-Te bond length is only increased by 0.04-0.07 Å. 88 The special bridging ability of R 104 The three ligands are Te-coordinated to AgI and the mean P-Te distance in the complex is only slightly elongated compared to that in the free ligand (Table 3). …”

Section: Coordination Complexesmentioning

confidence: 95%

“…The special bridging ability of R 3 PTe ligands is evinced in the 2:1 complex [Ag(μ- i Pr 3 PTe) 2 ][SbF 6 ], which forms a cationic coordination polymer . A 3:1 complex of the P III /P V monotelluride [ t Bu(H)NP III (μ-N t Bu) 2 P V (Te)N(H) t Bu] with AgI has been structurally characterized recently . The three ligands are Te -coordinated to AgI, and the mean P–Te distance in the complex is only slightly elongated as compared to that in the free ligand (Table ).…”

Section: Organophosphorus(v) Telluridesmentioning

confidence: 99%