A simple approach for synthesis of hollow mesoporous nanotubes loaded with metallic and magnetic nanoparticles: Only one step is required

Abstract

Hollow mesoporous polypyrrole (PPy)@Pd‐Fe3O4 nanotubes were prepared using MoO3 nanorods as hard templates in one step, in which construction of PPy nanotubes, preparation of Pd nanoparticles, synthesis of Fe3O4 nanoparticles and removal of MoO3 nanorods were combined together. To the best of our knowledge, this is the simplest approach for the synthesis of nanomaterials with catalytic activity, magnetic property and hollow mesoporous structure simultaneously. Although the preparation procedure was simplified, the catalytic activity and magnetic property were not sacrificed. In the catalytic reduction of 4‐nitrophenol, both reaction rate constant and turnover frequency were higher than those of previous reports. Importantly, the nanotubes could be easily separated from the reaction solution in the presence of a magnetic field, and saturation magnetization could be controlled by the amount of pyrrole monomer. After six recycles, the catalytic activity maintained 94.8% of that of the first run, indicating good stability and reusability.

Magnetic bentonite decorated with Pd nanoparticles and cross-linked polyvinyl pyridine as an efficient nanocatalyst for Suzuki coupling and 4-Nitrophenol reduction reactions

“…In this image, four separate peaks can be seen. The peaks at 338.3 and 344.2 eV are assigned to Pd 2+ or PdO, while the peaks at 336.4 and 342.8 eV correspond to metallic Pd 0 30 . On the other hand, in the spectrum of C1s (Fig.…”