A simple way for the electropolymerization of porphyrins

Giraudeau, A.; Schaming, Delphine; Hao, Jian; Farha, Rana; Goldmann, Michel; Ruhlmann, Laurent

doi:10.1016/j.jelechem.2009.10.018

Cited by 33 publications

(33 citation statements)

References 36 publications

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“…The polymetallic porphyrins have attracted attention in the elaboration of electrochemical sensors, due to their excellent electrocatalytic properties for several compounds [28][29][30].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical behavior of hydroquinone and catechol at glassy carbon electrode modified by electropolymerization of tetraruthenated oxovanadium porphyrin

Ribeiro

Vilarinho

Ramos

et al. 2015

Electrochimica Acta

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“…The polymetallic porphyrins have attracted attention in the elaboration of electrochemical sensors, due to their excellent electrocatalytic properties for several compounds [28][29][30].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical behavior of hydroquinone and catechol at glassy carbon electrode modified by electropolymerization of tetraruthenated oxovanadium porphyrin

Ribeiro

Vilarinho

Ramos

et al. 2015

Electrochimica Acta

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“…Electrochemical polymerization reactions have been studied for decades [10][11][12]. Although CPs can be polymerized by two methods via chemical and electrochemical techniques, they offer a better control over properties as they can be tailored by the changing experimental conditions, such as electrolyte, oxidation potential, solvent, etc.…”

Section: Introductionmentioning

confidence: 99%

Copolymer formation of 9-(2-(benzyloxy)ethyl)-9H-carbazole and 1-tosyl-1H-pyrrole coated on glassy carbon electrode and electrochemical impedance spectroscopy

Ateş

Uludag

Karazehir

2012

J Solid State Electrochem

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In this work, 9-(2-(benzyloxy)ethyl)-9H-carbazole (BzOCz) and 1-tosyl-1H-pyrrole (TsP) monomers were chemically synthesized and characterized by Fourier transform infrared reflectance (FTIR) and proton nuclear magnetic resonance ( 1 H-NMR) spectroscopy. BzOCz and TsP were electrocoated on glassy carbon electrode (GCE) in various molar fractions (X TsP 00.5, 0.83, 0.91, and 0.98) in 0.1 M sodium perchlorate/acetonitrile. The detailed characterization of poly (BzOCz-co-TsP) was studied by cyclic voltammetry, FTIRattenuated total reflection spectroscopy and electrochemical impedance spectroscopy (EIS). The effects of different molar fractions during the preparation of modified electrodes were studied by EIS technique. The AC impedance technique was used to determine the capacitive behaviors of modified GCE via Nyquist, Bode magnitude, and Bode phase plots. The highest low frequency capacitance value was obtained as C LF 023.94 μF cm −2 for X TsP 00.98. Therefore, synthesized copolymer has more capacitive behavior than its homopolymers, such as C LF 07.5 μF cm −2 for poly(BzOCz) and C LF 0 9.44 μF cm −2 for poly(TsP). In order to interpret the AC impedance spectra, R(Q(RW)) electrical equivalent circuit was employed with linear Kramers-Kronig test. A mechanism for electropolymerization has been proposed for copolymer formation.

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“…The properties of the linked porphyrins can be varied based on the choice of the nucleophilic bridge and the porphyrin substituents. 19 This group would later publish a similar paper describing the electropolymerization with the bridge already linked to one porphyrin, 20 and then another paper comparing the two methods. 21 The second paper used a bridge containing a polyoxometalate to produce one-and two-dimensional structures which were used for the photocatalytic reduction of Ag(I).…”

Section: Types Of Porphyrin Polymers and Preparative Methodsmentioning

confidence: 99%

Porphyrin polymers and organic frameworks

Day

Wamser

Walter

2015

Polymer International

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The versatility of porphyrins as optoelectronic or catalytic units makes them attractive elements for inclusion in functional materials. Polymers that include porphyrins have been created with a wide variety of structures and used in a wide range of applications. This review covers recent developments in the synthesis, characterization and applications of polymeric materials in which porphyrins are key components of the repeat units, including the rapidly growing area of metal-organic frameworks and related covalent organic frameworks. © 2015 Society of Chemical Industry Keywords: review; porphyrin; metal-organic framework; covalent organic framework PORPHYRINS AS FUNCTIONAL BUILDING BLOCKSThe porphyrin ring and its many structural relatives are common functional units in both natural and synthetic systems (Fig. 1). Porphyrins have a variety of properties that allow them to be useful in applications, especially their broad-ranging optoelectronic and catalytic capabilities. Furthermore, these properties are readily modulated by incorporation of various metals inside the ring or by substituent effects at various locations around the ring. In many cases, nature provides guidance for specific structure-function correlations and applications -the so-called biomimetic approaches. In nature, porphyrin (heme) units are typically embedded in a biological matrix that controls the environment of and access to the porphyrin. In synthetic systems, porphyrins in polymeric matrices have been developed in similar fashion to help control the specific application.In this review, we briefly cite previous reviews and summarize recent results regarding the synthesis, structure, properties and applications of polymeric porphyrins. We only include polymers that contain multiple porphyrin units as an integral part of the polymer, as opposed to polymeric matrices that are simply used to encapsulate individual porphyrin units. We also cover the rapidly growing field of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), where they specifically include porphyrins as a key component of the framework. Structures related to porphyrins (phthalocyanines, corroles, chlorins, etc.) and porphyrin dimers are not covered, but some porphyrin oligomers are discussed; reviews on many of these are available in the comprehensive series Handbook of Porphyrin Science.

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A simple way for the electropolymerization of porphyrins

Cited by 33 publications

References 36 publications

Electrochemical behavior of hydroquinone and catechol at glassy carbon electrode modified by electropolymerization of tetraruthenated oxovanadium porphyrin

Electrochemical behavior of hydroquinone and catechol at glassy carbon electrode modified by electropolymerization of tetraruthenated oxovanadium porphyrin

Copolymer formation of 9-(2-(benzyloxy)ethyl)-9H-carbazole and 1-tosyl-1H-pyrrole coated on glassy carbon electrode and electrochemical impedance spectroscopy

Porphyrin polymers and organic frameworks

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