A straightforward and rapid synthesis of polydithioacetals in the presence of chlorodimethylsilane

Luleburgaz, Serter; Akar, Emre; Tunca, Umit; Durmaz, Hakan

doi:10.1039/d3py01128c

Polym. Chem.

2024

DOI: 10.1039/d3py01128c

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A straightforward and rapid synthesis of polydithioacetals in the presence of chlorodimethylsilane

Serter Luleburgaz,

Emre Akar,

Umit Tunca

et al.

Abstract: Rapid synthesis of polydithioacetals (PDTAs) under mild conditions in high yields and varying molecular weights in the presence of chlorodimethylsilane (CDMS) is reported.

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Cited by 3 publications

References 72 publications

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Aromatic Poly(dithioacetal)s: Spanning Degradability, Thermostability, and High Refractive Index Towards Eco‐friendly Optics

Watanabe,

Yano,

et al. 2024

ChemSusChem

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In the quest for eco‐friendly optics, high refractive index polymers (HRIPs) with degradability have been one of the desirable optical materials for realizing eco‐friendly and efficient lighting technologies. However, it has been challenging for HRIPs to simultaneously realize thermostability, high refractive index (RI), visible transparency, and efficient degradability, all of which are essential for their practical use. In this context, we herein focus on aromatic poly(dithioacetal)s, composed of visible‐transparent yet degradable dithioacetal moieties and rigid diphenyl disulfide spacers, exhibiting moderately high Tg (> 60 °C), high RI (> 1.7), and colorless film features. In addition, poly(dithioacetal)s can balance (1) high stability under the operating conditions even upon heating and (2) quantitative degradability that can selectively yield cyclic low‐molecular‐weight products that can be further repolymerized upon further addition of an acid catalyst. These results provide a key concept for high refractive index polymers that allow on‐demand degradability and recyclability without compromising their high potential thermal and optical properties.

show abstract

Aromatic Poly(dithioacetal)s: Spanning Degradability, Thermostability, and High Refractive Index Towards Eco‐friendly Optics

Watanabe,

Yano,

et al. 2024

ChemSusChem

View full text Add to dashboard Cite

show abstract

Polythioacetals: From old chemistry to new perspectives

Akar,

Tunca,

Durmaz

2024

European Polymer Journal

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Rapid synthesis and post-polymerization modification of poly(vinylene sulfide) via sequential nucleophilic thiol-yne/ene click reactions

Kakas,

Sagdic,

Kumbaraci

et al. 2024

Journal of Macromolecular Science, Part A

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A straightforward and rapid synthesis of polydithioacetals in the presence of chlorodimethylsilane

Abstract: Rapid synthesis of polydithioacetals (PDTAs) under mild conditions in high yields and varying molecular weights in the presence of chlorodimethylsilane (CDMS) is reported.

Cited by 3 publications

References 72 publications

Aromatic Poly(dithioacetal)s: Spanning Degradability, Thermostability, and High Refractive Index Towards Eco‐friendly Optics

Aromatic Poly(dithioacetal)s: Spanning Degradability, Thermostability, and High Refractive Index Towards Eco‐friendly Optics

Polythioacetals: From old chemistry to new perspectives

Rapid synthesis and post-polymerization modification of poly(vinylene sulfide) via sequential nucleophilic thiol-yne/ene click reactions

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