2007
DOI: 10.1002/masy.200750856
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A Study of Simple RAFT Transfer Agents for the Polymerization of (Meth‐)acrylates and Acrylamides

Abstract: Summary: Within this work we aimed to study different RAFT agents for the potential use in coupled block copolymerization. Starting from S‐(thiobenzoyl)thioglycolic acid as a commercial available CTA it should easily be possible to modify the substituent due to the thiocarboxylic group. Different chain transfer agents CTA's were synthesized and RAFT polymerizations of methyl methacrylate, butyl acrylate, N,N‐dimethyl acrylamide, N,N‐diethyl acrylamide, and N‐isopropyl acrylamide were carried out and compared w… Show more

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Cited by 10 publications
(9 citation statements)
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“…St [184] MMA [88] 323 [185] 40 [186] S S O O St [186] St-b-MAH [186] St-b-MAH-b-NIPAM [186] 41* [187,188] S S (MMA) [64,187,189] BA [187] EHA [188] St [190] TBAM [191] DEAM [187] DMAM [187] NAM [191] NIPAM [187,189] BA/St [192] EHA-b-MA [188] TBAM-b-NAM [191] DMAM/NAS [193] NAM-b-TBAM [191] 42* S S Ph CN MMA [194] 376 [195] 376-b-MMA [195] BA [196] MMA [189] NIPAM [189] MMA-b-NIPAM [189] MMA/283 [197] MMA/284 [197] St/2VP [198] St/348 [199] THPA-b-St [200] THPA-b-St/373 [201] 44 [202] [200] 47 [203] …”
Section: Choice Of Raft Agentsmentioning
confidence: 99%
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“…St [184] MMA [88] 323 [185] 40 [186] S S O O St [186] St-b-MAH [186] St-b-MAH-b-NIPAM [186] 41* [187,188] S S (MMA) [64,187,189] BA [187] EHA [188] St [190] TBAM [191] DEAM [187] DMAM [187] NAM [191] NIPAM [187,189] BA/St [192] EHA-b-MA [188] TBAM-b-NAM [191] DMAM/NAS [193] NAM-b-TBAM [191] 42* S S Ph CN MMA [194] 376 [195] 376-b-MMA [195] BA [196] MMA [189] NIPAM [189] MMA-b-NIPAM [189] MMA/283 [197] MMA/284 [197] St/2VP [198] St/348 [199] THPA-b-St [200] THPA-b-St/373 [201] 44 [202] [200] 47 [203] …”
Section: Choice Of Raft Agentsmentioning
confidence: 99%
“…MAA [238] (MMA) [187] BA [187] AM [239] 341 [239] AM/341 [239] AM/340 [239] (DEAM) [187] (DMAM) [187] (NIPAM) [187] NIPAM [238] NIPAM-b-MAA [238] CO 2 CH 3 S S 77 [187] (MMA) [187] BA [187] DEAM [187] DMAM [187] (NIPAM) [187] …”
Section: *mentioning
confidence: 99%
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“…As we recently found, the LCST is also highly dependent on the applied pressure and can easily be tuned by the addition of cononsolvents [52]. NIPAam is also well controllable by RAFT-polymerization and forms block copolymers with BA [53,54]. …”
Section: Introductionmentioning
confidence: 99%