A Study on Chloride Corrosion Resistance of Reactive Powder Concrete (RPC) with Copper Slag Replacing Quartz Sand under Freeze–Thaw Conditions

Abstract

In order to study the influence of freeze–thaw cycles on chloride ion corrosion resistance of RPC with copper slag (CS) instead of quartz sand (QS), the 28d uniaxial compressive strength (UCS) of CSRPC with a different CS substitution rate was investigated by unconfined compression tests. The electric flux test method was used to study the chloride ion diffusion resistance of CSRPC after freeze–thaw cycles, and the pore size distribution was obtained through the nuclear magnetic resonance (NMR) method. Then, a mathematical relationship between the chloride ion diffusion coefficient and the pore fractal characteristic parameter T was established to study the effect of freeze–thaw cycles on chloride ion diffusion. Finally, SEM/EDS, XRD, and DTG methods were combined to study the influence of the distribution of Friedel’s salts generated after freeze–thaw cycles on chloride ion diffusion in CSRPC. The results indicate that CS has a micro aggregate effect and pozzolanic activity, which can effectively improve the chloride ion diffusion resistance of CSRPC after freeze–thaw cycles. In addition, the electric flux of CSRPC decreases with the increase in freeze–thaw cycles, and the chloride diffusion coefficient is closely related to the pore fractal dimension.