A study on the synthesis of alkaline copper(III)-periodate (DPC) complex with an overview of its redox behavior in aqueous micellar media

Chowdhury, Budhadeb; Mondal, Monohar Hossain; Barman, Milan Krishna; Saha, Bidyut

doi:10.1007/s11164-018-3643-2

Cited by 17 publications

(11 citation statements)

References 31 publications

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“…SLS (sodium laurylsulphate) is an Anionic surfactant which is widely used as penetration enhancer [ 26 – 28 ]. There are few specific properties that controls the efficiencies of surfactants as the penetration enhancers [ 29 ]-…”

Section: Surfactants In Dermatologymentioning

confidence: 99%

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Comprehensive Review on Applications of Surfactants in Vaccine Formulation, Therapeutic and Cosmetic Pharmacy and Prevention of Pulmonary Failure due to COVID-19

et al. 2022

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Our world is under serious threat of environmental degradation, climate change and in association with this the out breaks of diseases as pandemics. The devastating impact of the very recent COVID-19, The sharp increase in cases of Cancer, Pulmonary failure, Heart health has triggered questions for the sustainable development of pharmaceutical and medical sciences. In the search of inclusive and effective strategies to meet today’s demand, improvised methodologies and alternative green chemical, bio-based precursors are being introduced by scientists around the globe. In this extensive review we have presented the potentiality and Realtime applications of both synthetic and bio-based surfactants in bio-medical and pharmaceutical fields. For their excellent unique amphoteric nature and ability to solubilise in both organic and inorganic drugs, surfactants are one of the most potential candidates for bio-medicinal fields such as dermatology, drug delivery, anticancer treatment, surfactant therapy, vaccine formulation, personal hygiene care and many more. The self-assembly property of surfactants is a very powerful function for drug delivery systems that increases the bio-availability of the poorly aqueous soluble pharmaceutical products by influencing their solubility. Over the decades many researchers have reported the antimicrobial, anti-adhesive, antibiofilm, anti-inflammatory, antioxidant activities of surfactants regarding its utility in medicinal purposes. In some reports surfactants are found to have spermicidal and laxative activity too. This comprehensive report is targeted to enlighten the versatile applications of Surfactants in drug delivery, vaccine formulation, Cancer Treatment, Therapeutic and cosmetic Pharmaceutical Sciences and prevention of pulmonary failure due to COVID-19.

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Section: Surfactants In Dermatologymentioning

confidence: 99%

“…iv) Hydrophilicity of the head group of the surfactants For polar molecules surfactants with greater extent in hydrophilicity of the head is more effective than those with lesser hydrophilicity [ 29 , 30 ].…”

Section: Surfactants In Dermatologymentioning

confidence: 99%

Comprehensive Review on Applications of Surfactants in Vaccine Formulation, Therapeutic and Cosmetic Pharmacy and Prevention of Pulmonary Failure due to COVID-19

et al. 2022

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“…Similarly, KOH (BDH) and the other required solutions were prepared and stored safely. A study on the synthesis of alkaline copper (III) periodate (DPC) complex with an overview of its redox behavior in aqueous micellar media including stability and redox nature of Cu (III) periodate complex in a microheterogeneous environment has been reported in the recent literature [45].…”

Section: Synthesis Of Reagentsmentioning

confidence: 99%

Kinetics and Mechanism of Oxidation of Carbenicillin by Copper (III) Periodate Complex in Aqueous Alkaline Medium

Sahu

Mishra

2020

Journal of Chemistry

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Kinetics and mechanism of oxidation of carbenicillin by diperiodatocuprate [DPC-III] in aqueous alkaline medium were studied spectrophotometrically at 298 K and an ionic strength of 0.10 mol·dm−3. The reaction between DPC (III) and carbenicillin in the alkaline medium showed (CRBC : DPC-III) 1 : 4 stoichiometry. The reaction products were identified by the CHNS test, FT-IR, and LC-MS spectral reports. The reaction was of pseudo-first order with respect to DPC (III) and fractional order with respect to carbenicillin as well as alkali but retarding effect with respect to periodate. Monoperiodatocuprate (MPC-III) was found to be the main active species in the alkaline medium in the form of [Cu (H2IO6) (H2O)2]. Activation and thermodynamic parameters with respect to uncatalyzed rate constants (ku) and slow step rate constant (k) as well as equilibrium constants were determined. The plausible mechanism consistent with experimental results was proposed and discussed in detail.

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“…Copper, gold and platinum are the most promising candidate for electron transfer redox reactions and owing to their mimicking behaviour with the biological systems Cu (III)/Cu (II) redox couple can be used for the oxidation of glucose in BFCs [16]. As an alternative to noble metals, cobalt (Co) can also be considered as promising candidate for electrocatalysis.…”

Section: Design and Construction Of Electrodementioning

confidence: 99%

A Comprehensive Report on the Modern Applications of Inorganic Materials in Biofuel Cell Industry

2020

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In this review, a partial description of inorganic materials from different sources has been presented to understand the function of biofuel cells. One of today’s greatest problems is the deficiency of fossil fuels and particularly oil. While also concerning over the environmental issue one of the new and effective resources of energy is biofuel cells (BFCs). It is important to keep in mind that the recent progress in the application of inorganic materials in biofuel cells put the emphasis particularly on the electrode and redox behaviour. Here we have discussed the primary challenges of applying inorganic materials to use as electrode in BFCs for future technology. Recently the future of energy depends on the creative design of the stable and efficient systems to produce clean and renewable energy sources, such as biofuel cells. The physical challenges and associated problems lead our discussion in better engineering path as well as in theoretical approach to apply various inorganic substances in BFCs.

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A study on the synthesis of alkaline copper(III)-periodate (DPC) complex with an overview of its redox behavior in aqueous micellar media

Cited by 17 publications

References 31 publications

Comprehensive Review on Applications of Surfactants in Vaccine Formulation, Therapeutic and Cosmetic Pharmacy and Prevention of Pulmonary Failure due to COVID-19

Comprehensive Review on Applications of Surfactants in Vaccine Formulation, Therapeutic and Cosmetic Pharmacy and Prevention of Pulmonary Failure due to COVID-19

Kinetics and Mechanism of Oxidation of Carbenicillin by Copper (III) Periodate Complex in Aqueous Alkaline Medium

A Comprehensive Report on the Modern Applications of Inorganic Materials in Biofuel Cell Industry

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