A study on the Zirconium Compunds of some Dicarboxylic Acids

Abstract

From aqueous solution of Zr(NO,), and K;X (X-oxalate, malonate, malate, succinate, adipate and phthalate) taken in different molar proportions, the following compounds were prepared either by precipitation or by fractional crystallization methods. ZrO .

Rate and equilibrium data for the protonation of Vaska's compound and analogs

“…When ML" is a square-planar complex of a d8 metal atom, addition of H+ is usually accompanied by addition of a second group, X (eq 2). The role played by the group X in deter-ML4 + HX ^ML4HX (2) mining the rates and equilibria for (2) is not well-known.…”