A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates

Carboxylate–Hydrazone Mixed‐Linker Metal–Organic Frameworks: Synthesis, Structure, and Selective Gas Adsorption

“…Very recently, a one‐dimensional coordination polymer of copper(II) with both acetate and tridentate aroylhydrazone bridges was published . However, to the best of our knowledge, only a few aroylhydrazone‐bridged coordination polymers or MOFs with higher 2D or 3D dimensionalities have been reported . Similarly, aroylhydrazones were only very recently successfully implemented as linkers in 2D covalent organic frameworks (COFs) …”

Coordination polymers derived from alkali metal complexes of redox-active ligands

“…It provides for diverse supramolecular architectures for ions having the same oxidation state. [17][18][19][20][21] Low density magnesium-and lithium-organic coordination polymers reveal remarkable gas sorption properties. [22][23][24][25][26][27] Further, the low toxicity of the above mentioned metal ions makes their MOFs attractive for use in medicine.…”