A Systematic Crystallographic Study of the Host–Guest Interactions between Amines and Ti8 Polyoxotitanium Clusters
Xiaoqin Cui,
Huan Li,
Xin Li
et al.
Abstract:Host−guest interaction is a core concept in supramolecular chemistry. Amine is one of the most studied guest molecules, thanks to its abundant types and versatility as a hydrogen bonding donor. A thorough understanding of how the types of amines (primary, secondary, and tertiary) can affect the host−guest interaction is yet to be fully realized. Herein, we study crystallographically Ti 8 polyoxotitanium clusters that host primary, secondary, and tertiary amines and diamines. The number of guests in each cluste… Show more
Ti-oxide salicylate clusters with novel biloculate cages and exchangeable guests are reported. The guests influence the physiochemical properties and photocatalytic CO2/epoxide cycloaddition activities of the complexes.
Ti-oxide salicylate clusters with novel biloculate cages and exchangeable guests are reported. The guests influence the physiochemical properties and photocatalytic CO2/epoxide cycloaddition activities of the complexes.
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