A Thermo-Mechanical Study of Some Epoxy Adhesives Subjected to Combined Dynamic and Static Stresses

The physical aging behavior of a series of tyrosine-containing polyarylates was investigated as a function of the length of the alkyl pendent chain.The experiments were performed in a differential scanning calorimeter (DSC) at corresponding aging temperatures.It was found that the physical aging efficiency was strongly affected by small changes in the length of the pendent chain (2, 6, or 8 methylene units). For similar cooling rates from above Tg to below Tg and identical aging times, the enthalpy relaxation decreased with the length of the pendent chain. A free volume based explanation is suggested.

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Physical aging behavior of a series of biodegradable polymers as a function of the pendent-chain length

Bron

Fiordeliso

Kohn

1993 IEEE Annual Northeast Bioengineering Conference

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A Thermo-Mechanical Study of Some Epoxy Adhesives Subjected to Combined Dynamic and Static Stresses

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References 29 publications

Physical aging behavior of a series of biodegradable polymers as a function of the pendent-chain length

Physical aging behavior of a series of biodegradable polymers as a function of the pendent-chain length

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