A Wax-Elastomer Superwetting Membrane with Controllable Permeability: Toward Separating a Crude Oil-in-Water Emulsion from an Oil Field

Abstract

Smart superwetting membranes with finely tunable properties have attracted increased attention recently. However, they mostly focus on controllable wettability rather than controllable permeability. Also, the oil/ water separation performance is usually tested with laboratory-simulated samples, making it hard for the materials to meet practical applications. Herein, we fabricate thermally responsive superwetting membranes with wax, polystyrene-B-poly(ethylene-ran-butylene)-B-polys (SEBS, a kind of elastomer), and polydopamine (PDA) to realize emulsion separation with controllable permeability. Benefiting from the elasticity of SEBS and the fluidity difference of wax at different temperatures, the pore size of the membrane could be readily tuned, resulting in different permeability. The separation flux is 0 at ambient temperature (pore size 0.394 μm) and is over 100 L m −2 h −1 at a high temperature (pore size 0.477 μm). The membrane could realize the separation of simulated oil-in-water emulsions with efficiency above 99.4%. Furthermore, it successfully achieved crude oil-in-water emulsion separation from the oil field with oil residues of less than 300 mg L −1 in the temperature range of 60−80 °C, which is the actual working temperature adopted in industrial production. Such a polydopamine/wax-SEBS modified membrane with unprecedented controllable permeability can promote the development of the emulsion treatment field and provide a new direction for designing smart superwetting materials.