This review paper offers a comprehensive exploration of the symbiotic relationship between sustainable ground transportation and the dynamic realm of e-commerce. It delves into the critical intersection of environmental sustainability, technological innovation, and the evolving landscape of online commerce. This review synthesises cutting-edge technologies and strategies aimed at reducing energy requirements and environmental impacts in ground transportation. It explores advancements in lightweight materials, aerodynamics, and alternative fuels, emphasising their potential to mitigate the environmental footprint of vehicles. Additionally, the transition towards zero-emission vehicles, including battery-operated and fuel-cell vehicles, is analysed, taking into account both short-term and long-term outlooks. Simultaneously, the paper delves into the evolving landscape of e-commerce, which has become an integral part of modern consumer behaviour. It investigates the influence of e-commerce on ground transportation practices, emphasising the importance of efficient logistics, last-mile delivery, and sustainability in meeting the demands of the digital commerce era. By providing a holistic view of the challenges and opportunities at the nexus of sustainable ground transportation and e-commerce, this review paper offers valuable insights for researchers, policymakers, and industry stakeholders striving to shape a more sustainable and responsive future for ground transportation in the digital age.