Accurate detection of minute external strains is crucial for the development of efficient strain‐responsive sensors. However, designing a recyclable strain‐responsive sensor that simultaneously combines high sensitivity at low strain levels, excellent mechanical properties, and cost‐effectiveness remains a significant challenge. In this study, a strain‐responsive sensor named Cu2+‐crosslinked conductive acrylic resin (PAV/Cu2+‐CB‐x) has been designed by integrating conductive carbon black (CB) into an acrylic resin matrix crossed by Cu2+ to form a hierarchical dynamic network. Molecular dynamics (MD) simulations reveal that this molecular structure consists of multilevel strong and weak dynamic bonds: weaker coordination bonds and hydrogen bonds endow this sensor with exceptional sensitivity to minor strains, while stronger ionic bonds ensure superior mechanical properties. This meticulous molecular design enables the PAV/Cu2+‐CB‐x to exhibit a tensile strength of 7.16 MPa, an elongation at break of 355.50%, high conductivity of 0.294 S cm−1, and excellent sensitivity under the strains below 5% (gauge factor = 8.24). Additionally, this PAV/Cu2+‐CB‐x demonstrates a remarkable tensile strength recovery rate of 95.35% after multiple recycling. When applied as a strain‐responsive sensor, it can precisely capture movements of human joints and throat activity. This work provides a promising solution for future applications in motion detection and voice recognition.