Accelerated CO2 capture using immobilized carbonic anhydrase on polyethyleneimine/dopamine co-deposited MOFs

xv, jiabao; Zhang, Zeyang; Pang, Saizhao; Jia, Jiahui; Geng, Zixin; Wang, Ruirui; Li, Peikun; Bilal, Muhammad; Cui, Jiandong; Jia, Shiru

doi:10.1016/j.bej.2022.108719

Cited by 13 publications

(1 citation statement)

References 51 publications

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“…MOFs are employed in a multitude of applications, with the immobilization of proteins being one of the most promising [ 168 , 169 ]. CA has been encapsulated in different MOFs with different features, most of them being zeolites constituted by imidazolates, with acceptable or excellent results [ 149 , 154 , 170 ]. The enzyme encapsulation within MOFs generates enzyme diffusion through windows that have a smaller size than the cavity.…”

Section: Improving Ca Performance: Enzyme Immobilizationmentioning

confidence: 99%

Direct Biocatalytic Processes for CO2 Capture as a Green Tool to Produce Value-Added Chemicals

et al. 2023

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Direct biocatalytic processes for CO2 capture and transformation in value-added chemicals may be considered a useful tool for reducing the concentration of this greenhouse gas in the atmosphere. Among the other enzymes, carbonic anhydrase (CA) and formate dehydrogenase (FDH) are two key biocatalysts suitable for this challenge, facilitating the uptake of carbon dioxide from the atmosphere in complementary ways. Carbonic anhydrases accelerate CO2 uptake by promoting its solubility in water in the form of hydrogen carbonate as the first step in converting the gas into a species widely used in carbon capture storage and its utilization processes (CCSU), particularly in carbonation and mineralization methods. On the other hand, formate dehydrogenases represent the biocatalytic machinery evolved by certain organisms to convert CO2 into enriched, reduced, and easily transportable hydrogen species, such as formic acid, via enzymatic cascade systems that obtain energy from chemical species, electrochemical sources, or light. Formic acid is the basis for fixing C1-carbon species to other, more reduced molecules. In this review, the state-of-the-art of both methods of CO2 uptake is assessed, highlighting the biotechnological approaches that have been developed using both enzymes.

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Section: Improving Ca Performance: Enzyme Immobilizationmentioning

confidence: 99%

Direct Biocatalytic Processes for CO2 Capture as a Green Tool to Produce Value-Added Chemicals

et al. 2023

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Porous Nanomaterials for Enzyme Immobilization and Bioremediation Applications

Hussain,

Shahbaz,

Malik

et al. 2024

Microbes Based Approaches for the Management of Hazardous Contaminants

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Metal‐Organic Frameworks: A Potential Platform From Enzyme Immobilization to Mimetic Enzyme

Kuang,

Wang,

Bilal

et al. 2024

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Metal‐organic frameworks (MOFs) are a new class of organic‐inorganic hybrid materials that have been widely studied in the past two decades for their potential in catalysis. (1) In this review, we comprehensively summarize the synthesis, application, and potential advancements of MOFs in enzyme immobilization and mimetic enzymes. (2) We also discuss the design principles behind various MOF‐based biocatalysts, such as enzyme@MOF composites, and explore their utility in various reactions. (3) Additionally, we highlight the advantages of MOF materials as enzyme mimetics and provide a perspective on potential solutions to current challenges in MOF catalysis. (4) Ultimately, this review provides a general overview of the most recent advances in MOF‐based catalyst platforms, including enzyme@MOF biocatalysts and MOF‐based nanozymes, in various applications.

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Accelerated CO2 capture using immobilized carbonic anhydrase on polyethyleneimine/dopamine co-deposited MOFs

Cited by 13 publications

References 51 publications

Direct Biocatalytic Processes for CO2 Capture as a Green Tool to Produce Value-Added Chemicals

Direct Biocatalytic Processes for CO2 Capture as a Green Tool to Produce Value-Added Chemicals

Porous Nanomaterials for Enzyme Immobilization and Bioremediation Applications

Metal‐Organic Frameworks: A Potential Platform From Enzyme Immobilization to Mimetic Enzyme

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