Acetonyltriphenylphosphonium nitrate

Abstract

Crystals of the title salt, C21H20OP+·NO3 −, are composed of acetonyltriphenyl­phospho­nium cations and nitrate anions that mainly inter­act through electrostatic forces. The P atom in the cation has a slightly distorted tetra­hedral environment, with C—P—C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O—N—O angles of the nitrate anion is 359.99°, reflecting its trigonal–planar character. C—H⋯O hydrogen bonds help to consolidate the crystal packing.

Acetonyltriphenylphosphonium 2,3,5-triphenyltetrazolium tetrachloridocuprate(II)

“…49 (2) ] in normal ranges for the [CuCl 4 ] 2À complex anion (Clay et al, 1975;Laus et al, 2015). The P-C distances within the acetonyl triphenylphosphonium cation are similar to those reported for the same cation (Diop et al, 2013(Diop et al, , 2015. The range for the C-P-C angles [107.07 (9)-113.36 (10) ] indicate a small variation of the geometry for this cation.…”

“…Likewise, a few compounds with an acetonyl triphenylphosphonium or 2,3,5-triphenyltetrazolium cation have also been reported (Diop et al, 2013(Diop et al, , 2015Zhang et al, 2007). To expand on the available data on both the [CuCl 4 ] 2À anion as well as that on acetonyltriphenylphosphonium and 2,3,5-triphenyltetrazolium cations, we have initiated in this work the study of the interactions between CuCl 2 Á2H 2 O, acetonyl triphenylphosphonium chloride and 2,3,5-triphenyltetrazolium chloride, expecting the presence of both cations in the resulting compound.…”

Dimethyl N-Cyanodithioiminocarbonate and Triphenylphosphine Oxide Metal Halide Complexes: Molecular Crystal Elucidation

“…Acetonyltriphenylphosphonium can be used as a counter ion to stabilize an anion but may be an O-donor ligand coordinating to metal centers with its oxygen O atom. Very few crystalline compounds relating to acetonyltriphenylphosphonium have been encountered in the literature [12][13][14][15].…”

Nitrato Adducts and Derivatives: Synthesis and Infrared Study

“…Organo-and halotin (IV) compounds are known for their several applications [1]. Nitrato containing structures have been reported by several groups [2][3][4][5][6]. Seeking for new biologically active compounds, many groups including our have yet published several papers [7][8][9][10][11][12][13].…”