Highlights
S‐scheme heterojunction was fabricated through in‐situ solvothermal method
3D worm‐like BOR and 3D rocky stone CNPO composite exhibited high photoactivity through •O2−
3D/3D junction occurred through bridging bond for efficient charge separation
Waste H2O2 was turned into wealth •OH for mineralization of OTC and LVX
Bi0 plasmon assisted stability and H2O2 decomposition and Ov influenced its production