1953
DOI: 10.1021/ja01120a050
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Addition Compounds of Gallium Trichloride with Methyl Halides1,2

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Cited by 24 publications
(3 citation statements)
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“…native approach is based on a series of reports which show that singly-bridged bipolar structures must be considered as significant in non-aqueous solution. For aluminium, NMR studies 5 on this point are supported by Raman spectroscopy of Al 2 Br 6 in aromatic solvents, 16 while for Ga 2 X 6 , NMR spectra, 4 vapour pressure measurements, 17 and electron spin resonance spectroscopy 18 all support the structure shown as Fig. 1B.…”
Section: Methodsmentioning
confidence: 82%
“…native approach is based on a series of reports which show that singly-bridged bipolar structures must be considered as significant in non-aqueous solution. For aluminium, NMR studies 5 on this point are supported by Raman spectroscopy of Al 2 Br 6 in aromatic solvents, 16 while for Ga 2 X 6 , NMR spectra, 4 vapour pressure measurements, 17 and electron spin resonance spectroscopy 18 all support the structure shown as Fig. 1B.…”
Section: Methodsmentioning
confidence: 82%
“…The latter is the case in solids containing A12C17" or the corresponding bromide ion, Al2-Br7".12"15 Furthermore, vibrations arising from ionic bonds can only be observed in the IR spectra. 16 Such IR bands have (10) Torsi, G.; Mamantov, G.; Begun, G. M. Inorg. Nucl.…”
Section: Introductionmentioning
confidence: 99%
“…A third variation of the treatment is to use equation (5) in the form lklo (6) with / and 6 treated as constants and l and k as variables. This is essentially the same treatment as that described for equation (2).…”
Section: Outline Of the Methods And Examplesmentioning
confidence: 99%