2019
DOI: 10.1039/c8nh00293b
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Additive-manufacturing of 3D glass-ceramics down to nanoscale resolution

Abstract: An approach enabling nanoscale-additive manufacturing of inorganics based on phase transition via calcination of laser structured hybrid resin is proposed.

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Cited by 112 publications
(95 citation statements)
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“…The printed part can achieve a very high resolution of 100 nm. Post heat treatment enabled the formation of t-ZrO 2 crystalline phase and inorganic amorphous SiO 2 [54]. However, the authors did not state the application of the printed glass-ceramic.…”
Section: Additive Manufacturing (Am) Techniquementioning
confidence: 99%
“…The printed part can achieve a very high resolution of 100 nm. Post heat treatment enabled the formation of t-ZrO 2 crystalline phase and inorganic amorphous SiO 2 [54]. However, the authors did not state the application of the printed glass-ceramic.…”
Section: Additive Manufacturing (Am) Techniquementioning
confidence: 99%
“…As demonstrated in Ref. [29], the polymerized structure can be further changed and reduced in size by high temperature treatment after the femtosecond laser induced polymerization. Therefore, we anneal lens arrays at 120 • C (Figure 4a) and 130 • C (Figure 4b) for 1 h, respectively, as post heat treatment.…”
Section: Resultsmentioning
confidence: 89%
“…The surface of the lens is relatively smooth, showing the feasibility of this rapid fabrication technique. In order to further smoothen the surface of the lens, an effective and common thermal reflow strategy [28,29] is adopted. As demonstrated in Ref.…”
Section: Resultsmentioning
confidence: 99%
“…The femtosecond laser (fs laser) is a particularly promising approach from this point of view, in addition to its three-dimensional (3D) processing capability [7][8][9][10][11][12] and broad-spectrum material usability [13][14][15][16][17][18] . Sub-diffractionlimited feature sizes at a level of tens of nanometers based on multiphoton absorption 19,20 , thresholding 21 , shrinkage 22,23 , and stimulation emission depletion effect 24,25 , have also been realized in fs-laser-induced photocuring of polymers, which unfortunately are not applicable to solid materials. Optical near-field techniques provide an alternative super-resolution scheme by localizing light fields to nanometer scales with the physical shapes of sharp tips 26 , tiny apertures 27 , nanoparticles 28,29 , and small protrusions 30 .…”
Section: Introductionmentioning
confidence: 99%