Adsorption at Solid-Liquid Interfaces

Chattoraj, D. K.; Birdi, K. S.

doi:10.1007/978-1-4615-8333-2_8

Adsorption and the Gibbs Surface Excess 1984

DOI: 10.1007/978-1-4615-8333-2_8

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Adsorption at Solid-Liquid Interfaces

D. K. Chattoraj

K. S. Birdi

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Cited by 5 publications

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On the difference of equilibrium constants of DNA hybridization in bulk solution and at the solid‐solution interface

Oliviero

Federici

Colombi

et al. 2011

J of Molecular Recognition

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The origin of the difference between the equilibrium (affinity) constants of ligand-receptor binding in bulk solution and at a solid-solution interface is discussed in terms of Gibbsian interfacial thermodynamics. It results that the difference is determined by the surface work that the ligand-receptor interaction spends to accommodate surface binding, and in turn that the value of the surface equilibrium constant (strongly) depends on the surface that confines the event. This framework consistently describes a wide set of experimental observations of DNA surface hybridization, correctly predicting that within the surface work window for DNA hybridization, that ranges from -90 to 75 kJ mol(-1), the ratio between surface and bulk equilibrium constants ranges from 10(-16) to 10(13), spanning 29 orders of magnitude.

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On the difference of equilibrium constants of DNA hybridization in bulk solution and at the solid‐solution interface

Oliviero

Federici

Colombi

et al. 2011

J of Molecular Recognition

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show abstract

Endotoxin removal from Large-Volume Parenterals by various adsorbents

Baggerman¹,

Loos²,

Junginger³

1985

International Journal of Pharmaceutics

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The impact of interfacial interactions on poliovirus infectivity in detergent-treated cell monolayer cultures

Bossche

1995

Microbiological Research

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Adsorption at Solid-Liquid Interfaces

Cited by 5 publications

References 74 publications

On the difference of equilibrium constants of DNA hybridization in bulk solution and at the solid‐solution interface

On the difference of equilibrium constants of DNA hybridization in bulk solution and at the solid‐solution interface

Endotoxin removal from Large-Volume Parenterals by various adsorbents

The impact of interfacial interactions on poliovirus infectivity in detergent-treated cell monolayer cultures

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