Advanced Chemical Kinetics

Originally, the Arrhenius parameters were used to estimate the rate of chemical reactions. This article aims to develop the optimal temperature to inhibit specific zero-order kinetic reactions. The model extends the use of the Arrhenius equation and heat capacity modeling to derive the optimal temperature solution. Specifically, the Arrhenius equation, which connects temperature to reaction rates, and the heat equation are formulated to create a comprehensive heat accumulation model. Analytical modeling is utilized through a derivative process to provide optimization. According to a case study of carotene oxidation, the derivative solution proposes −1.73 °C and can extend the reaction time by 206,160.29 days compared to a solution with no temperature change. The derivative solution also offers higher advantages in practical application than setting the lowest temperature limit due to the high initial energy requirement. The temperature derivative solution exhibits a global optimum property because of its high heat accumulation and slower kinetic reactions. These slower kinetic reactions can prevent reactant substances from deteriorating, making them valuable for maintaining a chemical’s shelf life. The temperature solutions offer valuable insights for devising an effective temperature strategy to inhibit specific chemical processes and verifying the relationship between temperature and heat accumulation with curvature.

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Advanced Chemical Kinetics

Cited by 2 publications

References 84 publications

Biosorption potential of olive leaves as a novel low-cost adsorbent for the removal of hexavalent chromium from wastewater

Biosorption potential of olive leaves as a novel low-cost adsorbent for the removal of hexavalent chromium from wastewater

Temperature optimization model to inhibit zero-order kinetic reactions

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