2014
DOI: 10.1016/j.polymer.2013.12.039
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Advanced soap-free emulsion polymerization for highly pure, micron-sized, monodisperse polymer particles

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Cited by 59 publications
(28 citation statements)
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“…Among the various modifying routes and techniques, soap-free emulsion polymerization because of its environmental friendliness and high efficiency, has been widely accepted as one of the modifying routes [9][10][11][12][13]. In our previous researches, a novel and facial soap-free emulsion polymerization method was developed by using caprolactam modified casein as emulsifying component and stabilizer since it's proved having good emulsifying ability for acrylate monomers thus can improve the stability of as-prepared latex particles.…”
Section: Introductionmentioning
confidence: 99%
“…Among the various modifying routes and techniques, soap-free emulsion polymerization because of its environmental friendliness and high efficiency, has been widely accepted as one of the modifying routes [9][10][11][12][13]. In our previous researches, a novel and facial soap-free emulsion polymerization method was developed by using caprolactam modified casein as emulsifying component and stabilizer since it's proved having good emulsifying ability for acrylate monomers thus can improve the stability of as-prepared latex particles.…”
Section: Introductionmentioning
confidence: 99%
“…The nonuse of surfactants adhesive to polymer substances provides a merit of production of polymer particles with high purity [3]. Soap-free emulsion polymerization can be applied to production of polymer particles with high monodispersity in particle sizes.…”
Section: Introductionmentioning
confidence: 99%
“…However, no discussion has been made on the gel effect and particle interfacial energy for the self-sharpening M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT 4 of the particle growth. [1][2][3]9]. The present study is aimed at quantitative understanding of the self-sharpening in soap-free polymerization by considering the gel effect of radical polymerization and the interfacial energy of monomer-swollen polymer particles.…”
Section: Introductionmentioning
confidence: 99%
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“…Dobrowolska et al observed the particle coagulation phenomenon by high-resolution scanning electron microscopy (HR-SEM) and atomic force microscopy (AFM) and prepared nearly monodispersed polymer particles by adjusting the ionic strength and pH of the aqueous phase [13,14]. Telford et al also prepared polymer particles based on the particle coagulation mechanism [15][16][17]. As mentioned by Koper et al, Yamamoto et al reported that the addition of electrolyte effectively promotes hetero-coagulation and prevents secondary nucleation [18].…”
Section: Introductionmentioning
confidence: 99%