2018
DOI: 10.1002/ange.201811873
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Aggregation Behavior of a Six‐Membered Cyclic Frustrated Phosphane/Borane Lewis Pair: Formation of a Supramolecular Cyclooctameric Macrocyclic Ring System

Abstract: An ew six-membered cyclic frustrated phosphane/ borane Lewis pair was liberated from its HB(C 6 F 5 ) 2 adduct by treatment with vinylcyclohexane.T he system is an active frustrated Lewis pair that undergoes cycloaddition reactions with suitable p reagents and it splits dihydrogen. At room temperature in solution the new compound is am onomer, however,i nt he crystal and in solution at low temperature it aggregates to at hermodynamically favoured supramolecular macrocyclic cyclooctamer.

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Cited by 12 publications
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