Alkyne Coupling Induced by a Trinuclear Ruthenium Cluster: Synthesis and Structure of Di-μ-carbonyl-hexacarbonyl-μ3-(1,2,3,4-tetraphenyl-1,3-butadiene-1,4-diyl)-triruthenium(2 Ru—Ru), [Ru3(CO)8(C4Ph4)]

Capparelli, Mario V.; Sanctis, Ysaura De; Arce, Alejandro J.

doi:10.1107/s0108270195002861

Cited by 9 publications

(1 citation statement)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The dihedral angles between the ruthenacyclopentadiene plane and the cyclopentadienyl and phenyl planes are 70.2 and 49.8°, respectively. The Ru − Ru distances are 2.6646(5) and 2.6797(5) Å, and the Ru(2) − Ru(1) − Ru(3) angle is 88.612(12)°, which is comparable with those for other trinuclear ruthenacycle complexes. , The C(7) − C(7A) bond length is 1.482(4) Å, slightly longer than those found in the similar trinuclear ruthenacycle complexes (μ 3 -C 4 R 4 )Ru 3 (CO) 6 (μ-CO) 2 (R = Ph, Me) (1.460(7), 1.472(6) Å) . The C(8) − C(9) and C(10) − C(11) bond lengths (1.372(3), 1.349(4) Å) are close to the typical CC double bond and evidently shorter than other C − C bonds (1.478 − 1.497 Å) in the five-membered ring, supporting the cyclopentadiene structure.…”

Section: Resultssupporting

confidence: 52%

Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

Song

et al. 2010

Organometallics

View full text Add to dashboard Cite

Reactions of (phenylethynyl)lithium with substituted cyclopentenones gave the corresponding phenylethynyl-substituted cyclopentadienes 1,2-R2-4-(PhCC)C5H2 (R = Me (1a), Ph (1b)), which underwent subsequent deprotonation and transmetalation with ZrCl4 to yield the corresponding alkyne-functionalized zirconocene complexes {η5-[1,2-R2-4-(PhCC)C5H2]}2ZrCl2 (R = Me (2a), Ph (2b)). Thermal treatment of 2a,b with Ru3(CO)12 in refluxing benzene afforded the trinuclear complexes (3,4-R2C5H2)2(μ3-C4Ph2)Ru3(CO)6(μ-CO)2 (R = Me (3a), Ph (3b)) and the dinuclear complex (3,4-Ph2C5H2)2(μ-C4Ph2)Ru2(CO)5(μ-CO) (3c), via the unexpected cleavage of the two Cp′−Zr bonds. The crystal structures of 2b and 3a,c were determined by X-ray diffraction.

show abstract

Section: Resultssupporting

confidence: 52%

Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

Song

et al. 2010

Organometallics

View full text Add to dashboard Cite

show abstract

Die intermolekulare Aktivierung vonn-Alkanen durch einen dreikernigen Ru-Pentahydrid-Komplex – Bildung voncloso-Ruthenacyclopentadienkomplexen

et al. 2000

View full text Add to dashboard Cite

show abstract

Reaction of the Heteronuclear Cluster [Cp*IrRu₃(μ‐H)₂(CO)₁₀] with Alkynes: Stereoselective Binding

Srinivasan

Leong

2006

Eur J Inorg Chem

View full text Add to dashboard Cite

The reaction of the heteronuclear cluster [Cp*IrRu3(μ‐H)2(CO)10] (1) with the symmetrical alkynes RCCR (R = Ph, Et) afforded the butterfly clusters [Cp*IrRu3(CO)9(RCCR)] (2) and the trinuclear clusters [Cp*IrRu2(CO)7(RCCR)] (3) and [Ru3(CO)8(C4R4)] (4). The clusters 2 and 3 have the alkyne aligned parallel to an Ru–Ir bond. The reaction of 1 with unsymmetrical alkynes also afforded stereoselective binding of the alkyne such that the bulkier substituent was pointing away from the Cp*Ir moiety; with PhCCH, however, all three stereoisomers were obtained. With the bis‐silylated alkynes (R = SiMe3, SiEt3), loss of one trialkylsilyl group occurred to give [Cp*IrRu3(CO)9(HCCR)] and [Ru3(CO)9(μ‐H)(CCR)] (5). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

show abstract

Alkyne Coupling Induced by a Trinuclear Ruthenium Cluster: Synthesis and Structure of Di-μ-carbonyl-hexacarbonyl-μ3-(1,2,3,4-tetraphenyl-1,3-butadiene-1,4-diyl)-triruthenium(2 Ru—Ru), [Ru3(CO)8(C4Ph4)]

Cited by 9 publications

References 1 publication

Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

Die intermolekulare Aktivierung vonn-Alkanen durch einen dreikernigen Ru-Pentahydrid-Komplex – Bildung voncloso-Ruthenacyclopentadienkomplexen

Reaction of the Heteronuclear Cluster [Cp*IrRu₃(μ‐H)₂(CO)₁₀] with Alkynes: Stereoselective Binding

Contact Info

Product

Resources

About

Alkyne Coupling Induced by a Trinuclear Ruthenium Cluster: Synthesis and Structure of Di-μ-carbonyl-hexacarbonyl-μ3-(1,2,3,4-tetraphenyl-1,3-butadiene-1,4-diyl)-triruthenium(2 Ru—Ru), [Ru3(CO)8(C4Ph4)]

Cited by 9 publications

References 1 publication

Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

Alkyne-Functionalized Zirconocene Complexes: Synthesis, Structures, and Reactivities

Die intermolekulare Aktivierung vonn-Alkanen durch einen dreikernigen Ru-Pentahydrid-Komplex – Bildung voncloso-Ruthenacyclopentadienkomplexen

Reaction of the Heteronuclear Cluster [Cp*IrRu3(μ‐H)2(CO)10] with Alkynes: Stereoselective Binding

Contact Info

Product

Resources

About

Reaction of the Heteronuclear Cluster [Cp*IrRu₃(μ‐H)₂(CO)₁₀] with Alkynes: Stereoselective Binding