All-Solid-State Batteries Based on Glass-Ceramic Lithium Vanadate

Расковалов, А. А.; Saetova, N. S.

doi:10.1007/978-3-030-31581-8_13

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2021

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“…[4][5][6]. Vanadate glasses have the highest conductivity among semiconducting oxide glasses [7]; vanadate phosphate glasses are the most studied. At the same time, despite numerous works devoted to the study of vanadate-phosphate glasses in terms of their conductivity, insufficient attention has been paid to the explanation of some concentration dependence of non-electrical properties.…”

Section: Introductionmentioning

confidence: 99%

Structural changes in V₂O₅-P₂O₅ glasses: non-constant force field molecular dynamics and IR spectroscopy

2021

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Quasi-binary phosphate-vanadate glasses have been studied by both IR spectroscopy and a novel method of molecular dynamics with a non-constant force field. This method is used for the self-assembly of structural models of glasses. The obtained models and the glass network structure are analyzed quantitatively using element distribution by the number of R–O–R bonds (R is phosphorous or vanadium) and 4-, 6-, and 8-membered cycles. The bends on the concentration dependences of atoms distribution in the second coordination sphere agree well with changing the shape of IR spectra. Based on the cycle analysis, the formation of cycles is shown to be more characteristic for vanadate fragments that can form 4-membered cycles, which, according to Zachariasen’s rule, negatively affects glass-forming ability.

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Section: Introductionmentioning

confidence: 99%

Structural changes in V₂O₅-P₂O₅ glasses: non-constant force field molecular dynamics and IR spectroscopy

2021

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All-Solid-State Batteries Based on Glass-Ceramic Lithium Vanadate

Cited by 1 publication

References 189 publications

Structural changes in V₂O₅-P₂O₅ glasses: non-constant force field molecular dynamics and IR spectroscopy

Structural changes in V₂O₅-P₂O₅ glasses: non-constant force field molecular dynamics and IR spectroscopy

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All-Solid-State Batteries Based on Glass-Ceramic Lithium Vanadate

Cited by 1 publication

References 189 publications

Structural changes in V2O5-P2O5 glasses: non-constant force field molecular dynamics and IR spectroscopy

Structural changes in V2O5-P2O5 glasses: non-constant force field molecular dynamics and IR spectroscopy

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Structural changes in V₂O₅-P₂O₅ glasses: non-constant force field molecular dynamics and IR spectroscopy

Structural changes in V₂O₅-P₂O₅ glasses: non-constant force field molecular dynamics and IR spectroscopy