We report a measurement of the longitudinal alignment A L of the recoil nucleus in the µ − + 14 N(1 + , 0) → ν µ + 14 C(2 + , 7012) transition. The experiment was performed on the M9B beamline at the TRIUMF cyclotron via the measurement of the Doppler lineshape of the subsequent 14 C(2 + , 7012) → 14 C(0 + , 0) gamma-rays. We compare our result A L = 0.60 ± 0.11 to various model calculations, and discuss the sensitivity to the induced pseudoscalar coupling, second-forbidden effects and 2hω wavefunction admixtures.