Ammonia oxidation into nitrous oxide over Mn/Bi/Al catalyst

Nitrous oxide in oxidation chemistry and catalysis: application and production

“…The modeling was based on a quasihomogeneous steady-state approximation for the processes of heat and mass transfer in a twodimensional tubular reactor [112,117].…”

“…The results of the mathematical modeling gave rise to a pilot testing of the ammonia oxidation process using an installation consisting of a single tube of 4.5 m length [117].…”

“…Theoretically, the both selective oxidations could be done in a single step, simply adding one oxygen atom to the starting molecule. www.elsevier.com/locate/cattod Catalysis Today 100 (2005) [115][116][117][118][119][120][121][122][123][124][125][126][127][128][129][130][131] Application of alternative oxidants in the form of various oxygen-containing molecules opens new possibilities. The idea of this approach is as follows.…”

Liquid Phase Oxidation of Alkenes with Nitrous Oxide to Carbonyl Compounds

“…[15] The reaction is accomplished using a Mn/Bi/Al oxide catalyst, and 87 ± 88% selectivity to nitrous oxide has been achieved at almost complete conversion of ammonia. According to estimation, [16] the cost of active oxygen in N 2 O produced by this method is 4 times lower than its cost in H 2 O 2 .…”

Catalytic ammonia oxidation to nitrogen (I) oxide

“…In the recent years, nitrous oxide has become used as a mild oxidizer for partial oxidation of hydrocarbons, for example oxidation of benzene to phenol. That is why, the process for direct ammonia oxidation is of interest to numerous researchers [1][2][3][4]. For these applications the substantial attention is focused on the improvement of the N 2 O production technology.…”