Amphiphilic graft polymer with reduction breakable main chain prepared via click polymerization and grafting onto

Zhang, Xiaojin; Dai, Yu

doi:10.1007/s11051-018-4256-9

Cited by 4 publications

(3 citation statements)

References 40 publications

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“…Zhang and coworkers [ 132 ] took a similar approach when synthesizing amphiphilic PEG- and palmitate-grafted linear poly(urethane)s (PUs), with disulfide linkages along the main chain ( Figure 27 ). The amphiphilic polymers formed micelles in solution that were degradable upon being reduced.…”

Section: Reaction Types and Applicationsmentioning

confidence: 99%

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Thiol- and Disulfide-Based Stimulus-Responsive Soft Materials and Self-Assembling Systems

Beaupre

Weiss

2021

Molecules

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Section: Reaction Types and Applicationsmentioning

confidence: 99%

“… PEG-grafted PU amphiphilic polymers made by Zhang et al [ 132 ]. The main chains are cleavable upon reduction.…”

Section: Figurementioning

confidence: 99%

Thiol- and Disulfide-Based Stimulus-Responsive Soft Materials and Self-Assembling Systems

Beaupre

Weiss

2021

Molecules

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“…Branched polymers have different structures, such as graft polymers, − star polymers, − and highly branched polymers. − Due to structural differences, they exhibit different chemical properties even though they have the same chemical composition. Branched polymers are synthesized via diverse methods, which can be classified into step-growth polymerization, e.g., condensation–polymerization and addition polymerization, and chain-growth polymerization, e.g., radical polymerization, cationic polymerization, and anionic polymerization.…”

Section: Introductionmentioning

confidence: 99%

Branched Polymers: Synthesis and Application

Shao,

Li,

Liu

et al. 2023

Macromolecules

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Branched polymers have aroused great interest due to their less chain entanglement, high concentration of chain terminals, good solubility, and low viscosity in melts and solutions. In this Perspective, we highlight various synthesis strategies for branched polymers with different structures and discuss their applications in the field of solid polymer electrolytes for lithium batteries, coatings and membranes, surfactants, hydrogels, and so on. Here, we expect to arouse more synthesis approaches such as enzyme-catalyzed living radical polymerization and photoinitiated living radical polymerization and also to copolymerize monomers with different properties or to modify branched polymers in order to obtain functionalized branched polymers that can be produced under mild conditions.

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Click Chemistry in Polymer Science

Gür,

Abdelmohsen,

van Hest

2024

Click Chemistry in Polymer Science

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Since the introduction of “click chemistry” by Sharpless in 2001, it has been involved in a variety of chemical reactions, particularly in biological contexts, as illustrated by Bertozzi’s work. This chapter focuses on the applications of click chemistry in polymer science, with specific emphasis on cycloaddition and thiol-based reactions. Moreover, facilitating post-polymerization modifications like grafting, crucial for synthesizing drug–polymer conjugates and sensitive bioconjugates, will be discussed. In addition, the utility of click chemistry in amphiphilic polymer synthesis and facilitating controlled radical polymerization for various polymer architectures will be highlighted. Finally, the role of click chemistry in modifying supramolecular structures such as micelles and polymersomes will be shown.

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Amphiphilic graft polymer with reduction breakable main chain prepared via click polymerization and grafting onto

Cited by 4 publications

References 40 publications

Thiol- and Disulfide-Based Stimulus-Responsive Soft Materials and Self-Assembling Systems

Thiol- and Disulfide-Based Stimulus-Responsive Soft Materials and Self-Assembling Systems

Branched Polymers: Synthesis and Application

Click Chemistry in Polymer Science

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