2024
DOI: 10.1002/asia.202400168
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An Air‐Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P4

Beate G. Steller,
Clara A. Roller,
Michaela Flock
et al.

Abstract: Controlled insertion into a single P‐P bond of white phosphorus (P4) was achieved by employing a diaryl stabilized stannylene, Ar*2Sn (Ar* = 2,6‐bis(benzhydryl)‐4‐iPr‐phenyl). Conversions of the stannylene with P4 gave a non‐pyrophoric, air‐stable storage compound, which releases P4 quantitively upon irradiation with light (354 or 455 nm). Alternatively, the phosphorus cage is detached by reacting the storage compound with PhChChPh (Ch = Se, Te). Despite the recent advances in the directed conversion of P4 usi… Show more

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