An Air‐Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P4
Beate G. Steller,
Clara A. Roller,
Michaela Flock
et al.
Abstract:Controlled insertion into a single P‐P bond of white phosphorus (P4) was achieved by employing a diaryl stabilized stannylene, Ar*2Sn (Ar* = 2,6‐bis(benzhydryl)‐4‐iPr‐phenyl). Conversions of the stannylene with P4 gave a non‐pyrophoric, air‐stable storage compound, which releases P4 quantitively upon irradiation with light (354 or 455 nm). Alternatively, the phosphorus cage is detached by reacting the storage compound with PhChChPh (Ch = Se, Te). Despite the recent advances in the directed conversion of P4 usi… Show more
(NHC)→E coordination interactions are being explored in many chemical species, including carbones, and nitreones. (NHC)→S interactions are rare, but increasing attention is being paid to the compounds containing such interactions....
(NHC)→E coordination interactions are being explored in many chemical species, including carbones, and nitreones. (NHC)→S interactions are rare, but increasing attention is being paid to the compounds containing such interactions....
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