An anionic porphyrinylphosphonate-based hydrogen-bonded organic framework: optimization of proton conductivity through the exchange of counterions

Abstract

Hydrogen-bonded organic frameworks (HOFs) possessing a high crystallinity, simple synthetic procedure and easy regeneration provide a high efficiency as multifunctional systems including applications as proton conductors. Porphyrinylphosphonates having acidic moieties,...

Synthesis and characterization of two metallo-hydrogen-bonded organic frameworks with diverse structures and properties

“…Hydrogen-bonded organic frameworks (HOFs), an emerging type of crystalline porous material, have demonstrated promising applications in various fields such as catalysis, [1][2][3] sensing, [4][5][6][7][8] proton conductivity, 9,10 and adsorption. [11][12][13][14][15][16][17] The construction of HOFs relies on using functional groups with hydrogen-bonded acceptor and donor properties to create molecular building blocks.…”