The phase composition and crystal structures of heterophase Ti-Zr-Mn-V alloys were studied by scanning electron microscopy and X-ray diffraction. The structure of the as-cast and annealed alloys consisted of a Laves phase and a bcc solid solution. It is shown that the alloys interact with hydrogen at room temperature and a pressure of 0.23 MPa with an incubation period of 6-10 min and a duration of the absorption process of 10 min. The resulting hydrogen sorption capacity was more than 2 wt.%. Additional processing of the obtained hydrides could increase the hydrogen sorption capacity.