An Efficient and Reliable Gas Chromatographic Method for Measuring Liquid-Liquid Mutual Solubilities in Alkylbenzene + Water Mixtures: Toluene + Water from 303 to 373 K

Group contribution method for Henry's Law constant of aqueous hydrocarbons

“…Ž . Prausnitz 1986, ' Chen and Wagner 1994b, B Chandler et al 1998ethylbenzene, ᎏ this work, ⅷ Heidman et al 1985 al. 1986 , B Chen andWagner 1994c ;m-diethylbenzene, ᎏ this work, ⅷ Economou et al 1997 ;p-diisopropylbenzene, ᎏ this work, ⅷ Ž .…”

A new formulation of the predictive NRTL-PR model in terms of kij mixing rules. Extension of the group contributions for the modeling of hydrocarbons in the presence of associating compounds

“…[176] and hydrocarbon phase (II) ( ) [176] (CPA curves from Voutsas et al [193], k ij = −0.03). (b) Water (1)-toluene (2): aqueous phase (I) ( ) [160], (᭹) [177], ( ) [178] and hydrocarbon phase (II) ( ) [160], ( ) [177], (♦) [178] (CPA curves from Folas et al [194] with k ij = 0.0095, BETCR = 0.06).…”

Infinite dilution activity coefficients for benzene and toluene in water and in aqueous solutions of the protein denaturants urea and guanidine hydrochloride

“…For both benzene and toluene, starting from the freezing temperature of water, the limiting activity coefficient rises with increasing temperature, passes through a rather flat maximum at a temperature slightly below room temperature, and then continuously decreases with increasing temperature. For each of the two solutes, we fitted this temperature dependence to the following equation originating from the assumption of temperature independent heat capacity of solution: (27) , Bittrich et al; (28) •, Dutta et al; (29) · , Sanemasa et al; (30) , Sanemasa et al; (31) ·, Brown and Wasik; (32) , Bradley et al; (33) ♦ · , Pierotti and Labastre; (34) ♦, Bohon and Claussen; (26) ×, Anderson and Prausnitz. (35) The error bars correspond to the standard errors.…”