The integration of multimedia teaching refers to a novel teaching mode that combines multimedia, information resources, and information methods with content and teaching process in the teaching process with the guidance of contemporary educational ideas and organically unifies them on a spatial and temporal platform, so as to better accomplish the teaching tasks. However, with the deepening of network teaching and school connotation construction, various resources such as media materials, courseware, network courses, and teaching cases generated by education and teaching, as well as academic works, papers, patents, project results, and lectures of experts and professors gathered by scientific research, are increasing. In this situation, how to integrate teaching resources and courses to provide students with an independent learning platform and an information-based learning environment has become an urgent issue. For this problem, data mining has shown a strong vitality, and data mining can find out the potential connection between datasets. Association rule mining is the most researched and widely used data mining method. In this paper, we propose a multimedia network-assisted English integration of educational resources method based on association rule algorithm to give full play to the role of “multimedia technology” and realize the integration of traditional English teaching and information network culture, so as to achieve the purpose of optimizing English teaching. The experimental results show that with the increase of data volume, the average testing time of Apriori is reduced by 56.49 s compared with MapReduce, so the advantage of Apriori algorithm is more obvious. Therefore, this research can effectively provide students with rich and colorful personalized resources, realize high-performance interactive learning, and help students cultivate their independent learning ability as well as their lifelong learning habits.