Green supply chain management attaches great importance to the coordinated development of social economy and ecological environment, and requires enterprises to consider environmental protection factors in product design, packaging, procurement, production, sales, logistics, waste and recycling. Suppliers are the “source” of the entire supply chain, and the choice of green suppliers is the basis of green supply chain management, and their quality will directly affect the environmental performance of enterprises. The green supplier selection is a classical multiple attribute group decision making (MAGDM) problems. Interval-valued intuitionistic fuzzy sets (IVIFSs) are the extension of intuitionistic fuzzy sets (IFSs), and are utilized to depict the complex and changeable circumstance. To better adapt to complex environment, the purpose of this paper is to construct a new method to solve the MAGDM problems for green supplier selection. Taking the fuzzy and uncertain character of the IVIFSs and the psychological preference into consideration, the original MABAC method based on the cumulative prospect theory (CPT) is extended into IVIFSs (IVIF-CPT-MABAC) method for MAGDM issues. Meanwhile, the method to evaluate the attribute weighting vector is calculated by CRITIC method. Finally, a numerical example for green supplier selection has been given and some comparisons is used to illustrate advantages of IVIF-CPT-MABAC method and some comparison analysis and sensitivity analysis are applied to prove this new method’s effectiveness and stability.