An investigation into the adsorption of thorium(IV) from aqueous solutions by a carboxylate-functionalised graft copolymer derived from titanium dioxide-densified cellulose

Anirudhan, T.S.; Sreekumari, S; Jalajamony, S.

doi:10.1016/j.jenvrad.2012.10.001

Cited by 64 publications

(14 citation statements)

References 35 publications

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“…Besides the direct chemical modification, literature reveals the grafting of various monomeric units like acrylic acid, acrylamide, acrylonitrile, ethylenediamine, hydroxylamine, glycidyl monomers, urea, etc. followed by functionalization of the biomass surface so as to develop a better biosorbent [206][207][208][209]. Graft co-polymerization is a process in which an additional polymer is introduced into the backbone of the main polymeric chain.…”

Section: Design Of Better Biosorbentsmentioning

confidence: 99%

Adsorption isotherm and kinetics analysis of hexavalent chromium and mercury on mustard oil cake

Reddy

Chauhan

Chakraborty

2016

Environmental Engineering Research

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The biosorption process has been established as characteristics of dead biomasses of both cellulosic and microbial origin to bind metal ion pollutants from aqueous suspension. The high effectiveness of this process even at low metal concentration, similarity to ion exchange treatment process, but cheaper and greener alternative to conventional techniques have resulted in a mature biosorption technology. Yet its adoption to large scale industrial wastewaters treatment has still been a distant reality. The purpose of this review is to make in-depth analyses of the various aspects of the biosorption technology, staring from the various biosorbents used till date and the various factors affecting the process. The design of better biosorbents for improving their physico-chemical features as well as enhancing their biosorption characteristics has been discussed. Better economic value of the biosorption technology is related to the repeated reuse of the biosorbent with minimum loss of efficiency. In this context desorption of the metal pollutants as well as regeneration of the biosorbent has been discussed in detail. Various inhibitions including the multi mechanistic role of the biosorption technology has been identified which have played a contributory role to its non-commercialization.

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Section: Design Of Better Biosorbentsmentioning

confidence: 99%

Adsorption isotherm and kinetics analysis of hexavalent chromium and mercury on mustard oil cake

Reddy

Chauhan

Chakraborty

2016

Environmental Engineering Research

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“…Selulosa adalah polisakarida dan berat molekul tergantung pada sumber selulosa tersebut serta kondisi dan teknik isolasinya [1]. Teknik kopolimerisasi cangkok telah dimanfaatkan antara lain untuk mengubah sifat polimer induk dengan berbagai tujuan antara lain sebagai adsorben ion logam [2,3]. Dalam kopolimerisasi cangkok, rantai samping cangkok dengan kelompok fungsional kovalen melekat pada rantai utama dari backbone polimer untuk membentuk kopolimer bercabang [4].…”

Section: Pendahuluanunclassified

Modifikasi Selulosa Menggunakan Asamakrilat Dan Trimethallyl Isocianurate Dengan Metode Pra Iradiasi Peroksida

Suhartini

Saefumillah²,

Fadilla³

2018

jsmi

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MODIFIKASI SELULOSA MENGGUNAKAN ASAM AKRILAT DAN TRIMETHALLYL ISOCIANURATE DENGAN METODE PRA IRADIASI PEROKSIDA. Modifikasi selulosa dengan asam akrilat menggunakan pengikat silang Trimethallyl Isocianurate (TMAIC) dengan teknik kopolimerisasi cangkok pra-iradiasi-peroksida telah berhasil dilakukan. Penelitian ini bertujuan untuk mendapatkan adsorben ion logam berbasis selulosa. Pengikat silang TMAIC digunakan untuk meningkatkan ketahanan asam dan termal dari selulosa-g-AA. Kondisi optimum reaksi pencangkokan diperoleh pada dosis radiasi 40 kGy, konsentrasi TMAIC 0,5 %(w/v), konsentrasi monomer 10 %(v/v), suhu pencangkokan 90°C dan waktu pencangkokan 6 jam, dengan persen pencangkokan rata-rata sebesar 42,37 %. Pengembangan dalam air turun sebesar 36 % setelah penambahan TMAIC. Hasil sintesis kopolimer selulosa-TMAIC-g-AA telah berhasil dikarakterisasi dengan FT-IR, TGA dan SEM. Selulosa terikat silang dapat digunakan sebagai adsorben ion logam Pb 2+ , dengan kapasitas adsorpsi sebesar 2,60 mg/g pada waktu kontak 2 jam dan pH 5 (konsentrasi awal Pb 2+ 10 mg/L). Isoterm adsorpsi yang sesuai dengan adsorpsi Pb(II) dengan kopolimer adalah isoterm adsorpsi Langmuir yang berarti energi adsorpsi konstan di semua sisi kopolimer tersebut.

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“…PVA/TiO 2 /TMPTMS 238.1 [11] Aspergillus fumigatus 370.0 [28] Aspergillus niger 22.0 [29] Aspergillus terus 60.0 [29] Penicillium chrysogenum 142.0 [29] Rhizopus arrhizus 185.0 [29] Saccharomyces cerevisiae 119.0 [30] Calcined diatomite 121.2 [31] Flux calcined diatomite 116.6 [31] Carboxylate-functionalised graft copolymer derived from titanium dioxide-densified cellulose 92.2 [32] Crystalline tin oxide nanoparticles 62.5 [33] Moroccan oil shale impregnated with phosphoric acid 454.0 [34] Magnetic chitosan composite particles 312.5 [35] Pseudomonas biomass 476.2 [36] Activated carbon 21.3 [37] Poly(methacrylic acid) -grafted composite/bentonite 110.5 [38] P(4-vinyl pyridine) hydrogel 120.5 [39] P(4-vinyl pyridine)-co-2-hydroxyethylmetacrylate 64.9 [39] Cystoseira indica 169.5 [ A c c e p t e d M a n u s c r i p t …”

Section: Adsorbent Q Maxth (Mg/g) Referencementioning

confidence: 99%

Application of response surface methodology for thorium adsorption on PVA/Fe3O4/SiO2/APTES nanohybrid adsorbent

Mirzabe

Keshtkar

2015

Journal of Industrial and Engineering Chemistry

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An investigation into the adsorption of thorium(IV) from aqueous solutions by a carboxylate-functionalised graft copolymer derived from titanium dioxide-densified cellulose

Cited by 64 publications

References 35 publications

Adsorption isotherm and kinetics analysis of hexavalent chromium and mercury on mustard oil cake

Adsorption isotherm and kinetics analysis of hexavalent chromium and mercury on mustard oil cake

Modifikasi Selulosa Menggunakan Asamakrilat Dan Trimethallyl Isocianurate Dengan Metode Pra Iradiasi Peroksida

Application of response surface methodology for thorium adsorption on PVA/Fe3O4/SiO2/APTES nanohybrid adsorbent

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