Abstract:A molecular cage encapsulating gold nanoparticles is presented. Six benzylic thioethers are pointing into its cavity, stabilizing the particles in a 1:1 ligand-to-particle-ratio in excellent yields. They are bench stable...
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
This review focuses on pore engineering (intrinsic pore size, extrinsic porosity, and pore environment) in porous organic cages and summarizes the roles of pore engineering in various fields.
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