An Overview on Steps of Pesticide Residue Analysis and Contribution of the Individual Steps to the Measurement Uncertainty

Ömeroğlu, Perihan Yolci; Boyacıoğlu, Dilek; Ambrus, Árpád; Karaali, Artemis; Saner, Samim

doi:10.1007/s12161-012-9396-4

Cited by 23 publications

(6 citation statements)

References 62 publications

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“…The QuEChERS method was published in 2003 and the method has been widely used in residue analyses since. The QuEChERS-AOAC Official Method 2007.01 version has also been employed in residue analyses in agricultural commodities (Lehotay, 2007;Omeroglu et al, 2012;Polat & Tiryaki, 2019;Heshmati et al, 2020).…”

Section: Sample Preparation and Analysesmentioning

confidence: 99%

Reduction of some insecticide residues from grapes with washing treatments

Polat¹

2021

Turkish Journal of Entomology

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Insecticide application is the most common method of insect control in agriculture. Efficiency of washing treatments in reduction of insecticide (chlorpyrifos-methyl and lambda-cyhalothrin) residues from grapes were investigated in this study. The trial was established in a Sultana seedless vineyard in Sarıgöl District, Manisa Province, Turkey in 2020. Method verification was performed with the recovery, limit of quantification and precision. Pesticidefree grapes were spiked with 0.5, 1 and 5 times of MRL for pesticides. The recovery of chlorpyrifos-methyl and lambdacyhalothrin were 102 and 101% respectively. QuEChERS method yielded an overall-recovery of 101%. These figures were within the SANTE recovery limits (60-140%) and the detection limits of the insecticides were below the MRLs. Grapes in a vineyard were sprayed with insecticides four times and harvested 0, 2, 4 and 7 d after the last spray. Washing (tap water, citric and acetic acid) and ultrasonic cleaning treatments were applied to harvested grapes. Washing treatments decreased residue levels and reductions increased with prolonged washing durations. Reductions also decreased with prolonged harvest durations from the last spray. The citric and acetic acid washing, and ultrasoniccleaning methods provided more efficient reduction than washing with tap water.

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Section: Sample Preparation and Analysesmentioning

confidence: 99%

Reduction of some insecticide residues from grapes with washing treatments

Polat¹

2021

Turkish Journal of Entomology

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“…However, there is no specific legislation on the sampling of food contact materials and ceramic materials. Sampling method, analyte distribution in a lot, heterogeneity between primary samples, analyte loss during sampling, contamination, application differences between samplers, losses during storage, physical condition of the sample and sample temperature and pressure contribute to the sampling uncertainty (Yolci-Omeroglu et al, 2012). To the best of our knowledge, there is no reported study in the literature that shows the sampling uncertainty in migration analysis.…”

Section: Based On Aforementioned Scientific Backgrounds Europeanmentioning

confidence: 99%

Migration of lead and cadmium from ceramic kitchenware and estimation of sampling uncertainty

Bulut

Ömeroğlu

Acoğlu

et al. 2021

J. Food Process. Preserv.

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The aims of this study were (i) to evaluate the existing analysis capacity for lead and cadmium leached from ceramic articles, (ii) to determine the migration of lead and cadmium from glazed ceramic kitchenware sold on the Turkish market, (iii) to estimate the sampling uncertainty. Traditional ceramic cooking ware and Chinese breakfast hollowware were sampled randomly from different sales points located in Bursa in 2018 (n = 96). Ceramic articles were subjected to the migration conditions specified in the legislation, and the amount of lead and cadmium was determined with the inductively coupled plasma and mass spectrometry. It was found that the current analytical method can quantify lower levels of the metals with acceptable method performance parameters. The amount of the metals migrated were far below the current permissible limits set in the legislation. Relative sampling uncertainty was estimated as 66.1% and this result was related to the heterogeneity within a lot.

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“…Open Access this reason, the establishment regarding maximum residue limits (MRLs) of agricultural commodities (ACs) was required, which is strictly regulated in the several countries (Omeroglu et al, 2012). Furthermore, in order to ensure the safety assurance of circulated ACs, a continuous nation-wide pesticide residue monitoring program have been conducted .…”

Section: Research Articlementioning

confidence: 99%

Establishment of Analytical Method for Residues of Ethychlozate, a Plant Growth Regulator, in Brown Rice, Mandarin, Pepper, Potato, and Soybean Using HPLC/FLD

Lee¹,

Lee²,

Chae³

et al. 2015

Korean Journal of Environmental Agriculture

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BACKGROUND: Ethychlozate (ECZ) is a plant growth regulator of synthetic auxin for agricultural commodities (ACs). Accurate and sensitive method to determine ECZ in diverse ACs on global official purpose is required to legal residue regulation. As the current official method is confined to the limited type of crops with poor validation, this study was conducted to improve and extend the ECZ method using high-performance liquid chromatography (HPLC) in all the registered crops with method verification. METHODS AND RESULTS: ECZ and its acidic metabolite (ECZA) were both extracted from acidified samples with acetone and briefly purified by dichloromethane partition. ECZ was hydrolyzed to form ECZA and the combined ECZA was finally purified by ion-associated partition including hexane-washing. The instrumental quantitation was performed using HPLC/ FLD under ion-suppression of ECZA with no interference by sample co-extractives. The average recoveries of intra-and inter-day experiment

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An Overview on Steps of Pesticide Residue Analysis and Contribution of the Individual Steps to the Measurement Uncertainty

Cited by 23 publications

References 62 publications

Reduction of some insecticide residues from grapes with washing treatments

Reduction of some insecticide residues from grapes with washing treatments

Migration of lead and cadmium from ceramic kitchenware and estimation of sampling uncertainty

Establishment of Analytical Method for Residues of Ethychlozate, a Plant Growth Regulator, in Brown Rice, Mandarin, Pepper, Potato, and Soybean Using HPLC/FLD

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