An structural study of Pt•••H –C(sp3) anagostic interaction in heteroscorpionate complexes

Lagunas-Simón, Beatriz; González-Montiel, Simplicio; Salazar-Pereda, Verónica; Vásquez-Pérez, José Manuel; Cruz-Borbolla, Julián

doi:10.1016/j.molstruc.2023.137289

Journal of Molecular Structure

2024

DOI: 10.1016/j.molstruc.2023.137289

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An structural study of Pt•••H –C(sp3) anagostic interaction in heteroscorpionate complexes

Beatriz Lagunas-Simón,

Simplicio González-Montiel,

Verónica Salazar-Pereda

et al.

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Chiral Biaryl N-Heterocyclic Carbene–Palladium Catalysts with Anagostic C–H···Pd Interaction for Enantioselective Desymmetric C–N Cross-Coupling

Han,

Ryu,

Kang

et al. 2024

Org. Lett.

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Novel chiral biaryl imidazo[1,5-a]pyridine carbene− palladium complexes (ImPy−Pd) featuring an anagostic C−H•••Pd interaction and a C5-aryl substituent have been developed and successfully applied to the Pd-catalyzed enantioselective desymmetric C−N cross-coupling of malonamide derivatives, providing chiral 3,4-dihydroquinoline-2-ones with quaternary stereocenters in high yields (≤99%) and enantioselectivities (≤97:3 er). The chiral catalyst exerts stereocontrol by restricting the rotation of substituents around the metal center through anagostic interactions with sterically bulky substituents.

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Chiral Biaryl N-Heterocyclic Carbene–Palladium Catalysts with Anagostic C–H···Pd Interaction for Enantioselective Desymmetric C–N Cross-Coupling

Han,

Ryu,

Kang

et al. 2024

Org. Lett.

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show abstract

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An structural study of Pt•••H –C(sp3) anagostic interaction in heteroscorpionate complexes

Cited by 1 publication

References 32 publications

Chiral Biaryl N-Heterocyclic Carbene–Palladium Catalysts with Anagostic C–H···Pd Interaction for Enantioselective Desymmetric C–N Cross-Coupling

Chiral Biaryl N-Heterocyclic Carbene–Palladium Catalysts with Anagostic C–H···Pd Interaction for Enantioselective Desymmetric C–N Cross-Coupling

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