An unprecedented two-dimensional Eu(III) coordination polymer Eu(OOC–C5H4N–CH2–CH2–COO)(OOC–COO)·2H2O formed by in situ reaction of fumaric acid and isonicotinic acid: Crystal structure and luminescent properties

Yun, De; Zeng, Heping; Li, Ying Wei; Li, Jing

doi:10.1016/j.solidstatesciences.2009.02.009

Cited by 11 publications

(3 citation statements)

References 62 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…10 The oxalate ligand could be formed via a decarboxylation reaction. 11 Such a metal-organic network also acts as a luminescent receptor for reversible and selective molecular sensing.…”

Section: Introductionmentioning

confidence: 99%

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

Wang

et al. 2010

CrystEngComm

Self Cite

122

View full text Add to dashboard Cite

A new microporous europium-containing metal-organic framework [Eu 2 (m 2 -pzdc)(m 4 -pzdc)(m 2ox)(H 2 O) 4 ]$8H 2 O (1) (H 2 pzdc ¼ 2,5-pyrazinedicarboxylic acid, H 2 ox ¼ oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schl€ afli symbol of (4$6 4 $8) 2 (4 2 $6 2 $8 2 ), which exhibits a reversible and highly selective sensing function with respect to acetone.

show abstract

“…10 The oxalate ligand could be formed via a decarboxylation reaction. 11 Such a metal-organic network also acts as a luminescent receptor for reversible and selective molecular sensing.…”

Section: Introductionmentioning

confidence: 99%

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

Wang

et al. 2010

CrystEngComm

Self Cite

122

View full text Add to dashboard Cite

show abstract

“…Then, the oxalate anion was formed via the in situ reductive coupling of CO 2 . Actually, such in situ reactions have been reported in literature [Li et al, 2006;Ma, Zeng et al, 2009]. As depicted in Fig.…”

Section: S1 Commentmentioning

confidence: 91%

“…For heterometallic complexes constructed from pyrazine-2-carboxylic acid, see: Deng et al (2008); Feng & Wen (2009). For general background to in situ reactions, see: Li et al (2006); Ma, Zeng et al (2009).…”

Section: Related Literaturementioning

confidence: 99%

catena-Poly[[[tetraaquaerbium(III)]-μ-oxalato-κ⁴O¹,O²:O^1′,O^2′] [bromidobis(pyrazine-2-carboxylato-κ²N¹,O)cuprate(II)] tetrahydrate]

Yang

2010

Acta Cryst E

View full text Add to dashboard Cite

In the title heterometallic complex, {[Er(C2O4)(H2O)4][CuBr(C5H3N2O2)2]·4H2O}n, the ErIII atom is eight-coordinated by four O atoms from two centrosymmetric oxalate ligands and four water molecules, displaying a bicapped trigonal-prismatic geometry. The oxalate ligands bridge the Er atoms into a polymeric cationic chain along [110]. The CuII atom is five-coordinated in a square-pyramidal geometry by two pyrazine-2-carboxylate ligands and a Br atom, forming a discrete anion. The polymeric cations, complex anions and uncoordinated water molecules are self-assembled into a three-dimensional supramolecular network through O—H⋯N, O—H⋯O and O—H⋯Br hydrogen bonds.

show abstract

Luminescent electrospun composite nanofibers of [Eu(TFI)3(Phen)]·CHCl3/polyvinylpyrrolidone

Yan

Wang

et al. 2013

J Mater Sci

View full text Add to dashboard Cite

An unprecedented two-dimensional Eu(III) coordination polymer Eu(OOC–C5H4N–CH2–CH2–COO)(OOC–COO)·2H2O formed by in situ reaction of fumaric acid and isonicotinic acid: Crystal structure and luminescent properties

Cited by 11 publications

References 62 publications

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

catena-Poly[[[tetraaquaerbium(III)]-μ-oxalato-κ⁴O¹,O²:O^1′,O^2′] [bromidobis(pyrazine-2-carboxylato-κ²N¹,O)cuprate(II)] tetrahydrate]

Luminescent electrospun composite nanofibers of [Eu(TFI)3(Phen)]·CHCl3/polyvinylpyrrolidone

Contact Info

Product

Resources

About

An unprecedented two-dimensional Eu(III) coordination polymer Eu(OOC–C5H4N–CH2–CH2–COO)(OOC–COO)·2H2O formed by in situ reaction of fumaric acid and isonicotinic acid: Crystal structure and luminescent properties

Cited by 11 publications

References 62 publications

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules

catena-Poly[[[tetraaquaerbium(III)]-μ-oxalato-κ4O1,O2:O1′,O2′] [bromidobis(pyrazine-2-carboxylato-κ2N1,O)cuprate(II)] tetrahydrate]

Luminescent electrospun composite nanofibers of [Eu(TFI)3(Phen)]·CHCl3/polyvinylpyrrolidone

Contact Info

Product

Resources

About

catena-Poly[[[tetraaquaerbium(III)]-μ-oxalato-κ⁴O¹,O²:O^1′,O^2′] [bromidobis(pyrazine-2-carboxylato-κ²N¹,O)cuprate(II)] tetrahydrate]