A new method for generating frequency-octupling millimeter-wave (mm-wave) vector signals in optical fields via a Sagnac loop is proposed. In this scheme, two orthogonally polarized fourth order sidebands can be obtained through an integrated dual-polarization quadrature phase shift keying (DP-QPSK) modulator. The two optical sidebands are sent into an I/Q modulator-based Sagnac loop. The I/Q modulator is modulated by a 16QAM baseband signal. In the Sagnac loop, one of the sidebands is modulated by the baseband vector signal along one direction, and the other sideband is unmodulated along the opposite direction because the I/Q modulator has the traveling-wave nature. Thanks to this modulation property and the symmetrical structure of the Sagnac loop, a frequency-octupling mm-wave vector signal that is free from interband beating and fiber chromatic dispersion interference can be generated by the photodetector (PD). After simulating a 20 km single-mode fiber (SMF) transmission, the generated frequency-octupling vector signal was good in function.