Subcarrier mapping (SCM) is considered to be crucial for capacity-maximization in an orthogonal frequency division multiplexing (OFDM) relaying network. Although SCM in an OFDM system has been investigated extensively, nevertheless, the outage probability and outage capacity analysis of the system is not yet available in the literature. This paper presents the outage analysis of a dual-hop OFDM relay system with ordered subcarrier paring schemes, i.e., worst-to-best (WTB) SCM and best-to-best (BTB) SCM. Accurate close-form expressions are derived for end-to-end outage while considering a dual-hop fixed gain amplify-and-forward (AF) relaying system with Rayleigh fading channel model. The first and second moments of end-to-end signal-to-noise ratio (SNR) and capacity are derived for WTB SCM and BTB SCM schemes while approximating the probability distribution function (PDF) of total capacity of each subcarrier pair by Gaussian distribution. The outage performances of these schemes are compared with balanced links, i.e., when the SNR is same for both hops, as well as unbalanced links, i.e., when the SNR of the second hop is one half of the SNR of the first hop. The numerical results validate the analysis in Rayleigh fading channel.